3-(trichlorosilyl)-3-[chloro(dimethyl)silyl]-4-(trichlorosilyl)-exo-tricyclo[4.2.1.0(2,5)]non-7-ene

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 3-(trichlorosilyl)-3-[chloro(dimethyl)silyl]-4-(trichlorosilyl)-exo-tricyclo[4.2.1.0(2,5)]non-7-ene
• 英文别名: trichloro-[(1R,2R,5S,6S)-3-[chloro(dimethyl)silyl]-4-trichlorosilyl-3-tricyclo[4.2.1.02,5]non-7-enyl]silane
• 化学式: C₁₁H₁₅Cl₇Si₃
• 分子量: 479.668
• InChiKey: PXHOYBRJYOMVEN-NWMPLJELSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.84
• 重原子数：
  21
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.82
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  trichloro-[1-[chloro(dimethyl)silyl]-2-trichlorosilylethenyl]silane 、 四环庚烷 反应 1200.0h， 以95%的产率得到3-(trichlorosilyl)-3-[chloro(dimethyl)silyl]-4-(trichlorosilyl)-exo-tricyclo[4.2.1.0(2,5)]non-7-ene
  参考文献：
  名称：

  Synthesis of silicon-substituted tricyclononenes

  摘要：

  A new series of tricyclononene derivatives with two and three silyl groups are successfully synthesized via [2 sigma+2 sigma+2 pi]-cycloaddition of silylethylenes to quadricyclane. The activity of the silylethylenes in the cycloaddition reactions was estimated. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2011.09.009

文献信息

• Synthesis of silicon-substituted tricyclononenes
  作者：M.V. Bermeshev、A.V. Syromolotov、M.L. Gringolts、V.G. Lakhtin、E.Sh. Finkelshtein

  DOI：10.1016/j.tetlet.2011.09.009

  日期：2011.11

  A new series of tricyclononene derivatives with two and three silyl groups are successfully synthesized via [2 sigma+2 sigma+2 pi]-cycloaddition of silylethylenes to quadricyclane. The activity of the silylethylenes in the cycloaddition reactions was estimated. (C) 2011 Elsevier Ltd. All rights reserved.