(3aalpha,4beta,6aalpha)-N,N-二[2-(二苯基膦基)乙基]六氢-2-氧代-1H-噻吩并[3,4-d)咪唑-4-戊酰胺 | 66561-97-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 生物素及其衍生物
• 中文名称: (3aalpha,4beta,6aalpha)-N,N-二[2-(二苯基膦基)乙基]六氢-2-氧代-1H-噻吩并[3,4-d)咪唑-4-戊酰胺
• 英文名称: N,N-Bis[2-(diphenylphosphino)ethyl]-5-(2-oxohexahydro-1H-thieno[3,4-d]imidazol-4-yl)pentanamide
• 英文别名: N,N-bis(2-diphenylphosphanylethyl)-5-(2-oxo-1,3,3a,4,6,6a-hexahydrothieno[3,4-d]imidazol-4-yl)pentanamide
• CAS: 66561-97-5
• 化学式: C₃₈H₄₃N₃O₂P₂S
• 分子量: 667.8
• InChiKey: YQGVXWZSNIQEOR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  46
• 可旋转键数：
  15
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.32
• 拓扑面积：
  86.7
• 氢给体数：
  2
• 氢受体数：
  3

文献信息

• Process for the partial hydrogenation of fatty acid esters
  申请人：Papadogianakis Georgios

  公开号：US20100022664A1

  公开（公告）日：2010-01-28

  Suggested is a process for the manufacture of unsaturated fatty acid alkyl esters or glycerides having a total content of C 18:1 of about 30 to about 80 Mol-% by partial hydrogenation of unsaturated fatty acid esters having a total content of (C18:2+C18:3) of at least 65 Mol-%—calculated on the total amount of C18 moieties in the ester—which is characterised in that the hydrogenation is conducted in an aqueous/organic two phase system in the presence of a water soluble catalyst consisting of a Group VIII metal and a hydrophilic ligand.