1,3-二[[(2-丙烯基氧基)羰基]氧基]-2,2-二[[[(2-丙烯基氧基)羰基]氧基]甲基]丙烷 | 71426-88-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机碳酸及其衍生物
• 中文名称: 1,3-二[[(2-丙烯基氧基)羰基]氧基]-2,2-二[[[(2-丙烯基氧基)羰基]氧基]甲基]丙烷
• 英文名称: Carbonic acid, 2,2-bis((((2-propenyloxy)carbonyl)oxy)methyl)-1,3-propanediyl di-2-propenyl ester
• 英文别名: [3-prop-2-enoxycarbonyloxy-2,2-bis(prop-2-enoxycarbonyloxymethyl)propyl] prop-2-enyl carbonate
• CAS: 71426-88-5
• 化学式: C₂₁H₂₈O₁₂
• 分子量: 472.4
• InChiKey: BMNNFEWUVQWGFY-UHFFFAOYSA-N

物化性质

• 沸点：
  524.0±50.0 °C(Predicted)
• 密度：
  1.196±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  33
• 可旋转键数：
  24
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  142
• 氢给体数：
  0
• 氢受体数：
  12

文献信息

• Liquid and polymerizable composition suitable for the production of organic glasses endowed with high abrasion strenght
  申请人：ENICHEM SYNTHESIS S.p.A.

  公开号：EP0241997A2

  公开（公告）日：1987-10-21

  A liquid composition polymerizable under the influence of free-radical initiators to yield crosslinked polymers useful as organic glasses endowed with high abrasion strength, contains an oligomer allyl-carbonate with two end allyl groups, a monomer allyl-carbonate with at least four end allyl groups and possibly also one or more reactive diluents containing groups of allyl, vinyl or methacryl type.

  一种可在自由基引发剂作用下进行聚合的液体组合物，可产生交联聚合物，用作具有高耐磨强度的有机玻璃，该组合物包含有两个烯丙基末端基团的烯丙基碳酸酯低聚物、至少有四个烯丙基末端基团的烯丙基碳酸酯单体，可能还有一种或多种含有烯丙基、乙烯基或甲基丙烯酸酯类基团的活性稀释剂。
• Liquid composition polymerizable to yield organic glasses endowed with high thermal stability
  申请人：ENICHEM SYNTHESIS S.p.A.

  公开号：EP0302537A1

  公开（公告）日：1989-02-08

  A liquid composition polymizable by the free-radical polymerization route, with a low shrinkage, to yield organic glasses endowed with high thermal stability, is constituted by the product of transesterification of diallyl-carbonate (A) with a mixture of diol (B) and of a polyol (C) containing from 3 to 6 hydroxy groups in the molecule, or a mixture of a diol (B) with a cycloaliphatic diol (C′), by operating with a molar ratio of A/(B+C) or A/(B+C′) equal to, or larger than, 3/1, and with an amount of (C) in the (B+C) mixture equal to, or smaller than, 70% by weight, or with an amount of (C′) in the (B +C′) mixture equal to, or smaller than, 90% by weight.

  一种可通过自由基聚合途径聚合的液体组合物，具有低收缩性，可生成具有高热稳定性的有机玻璃，由碳酸二烯丙酯(A)与二元醇(B)和分子中含有 3 至 6 个羟基的多元醇(C)的混合物进行酯交换反应的产物构成、或二元醇（B）与环脂族二元醇（C′）的混合物，操作时 A/(B+C)或 A/(B+C′)的摩尔比等于或大于 3/1、(B+C)混合物中(C)的含量等于或小于70%(重量)，或(B+C′)混合物中(C′)的含量等于或小于90%(重量)。
• Process for preparing organic glasses
  申请人：GREAT LAKES CHEMICAL ITALIA S.r.l.

  公开号：EP0346996A2

  公开（公告）日：1989-12-20

  Organic glasses and surface coatings are prepared, with short hardening cycles, by submitting to the action of U.V. light a liquid polymerizable composition containing at least one di-(allyl carbonate) or poly-(allyl carbonate) of a diol or polyol, a photoinitiator and a vinyl ester monomer and/or an organic peroxide. The composition can additionally contain small amounts of an organic compound selected from among those compounds which are used in the art in order to stabilize the organic polymers to the degrading action of U.V. light. The composition is preferably heated before being treated with U.V. iight.

  将含有至少一种二元醇或多元醇的二碳酸（烯丙基）酯或多碳酸（烯丙基）酯、光引发剂和乙烯基酯单体和/或有机过氧化物的液态可聚合组合物置于紫外光下，可制备出硬化周期短的有机玻璃和表面涂层。 此外，该组合物还可以含有少量的有机化合物，这些化合物可以从本领域常用的化合物中选出，以稳定有机聚合物，使其不受紫外光的降解作用影响。 在用紫外光处理之前，最好对组合物进行加热。
• Polymerizable composition for optical articles
  申请人：PPG Industries Ohio, Inc.

  公开号：US10294318B2

  公开（公告）日：2019-05-21

  A polymerizable composition includes at least one first monomer and at least one second monomer, wherein the at least one first monomer includes an isohexide bis(allyl carbonate) monomer, and wherein the at least one second monomer includes one or more ethylenic unsaturations. Another polymerizable composition includes the reaction product of an isohexide bischloroformate; at least one polyol; allyl alcohol; and, optionally, at least one polychloroformate. An exemplary polymerizable composition includes the transesterification reaction product of an isohexide; diallyl carbonate; and at least one polyol. A polymerizate including the polymerizable composition and an optical article including the polymerizable composition are also provided.

  一种可聚合组合物包括至少一种第一单体和至少一种第二单体，其中至少一种第一单体包括异己双（碳酸烯丙酯）单体，其中至少一种第二单体包括一种或多种乙烯基不饱和物。另一种可聚合组合物包括异己双氯甲酸酯、至少一种多元醇、烯丙基醇和可选的至少一种聚氯甲酸酯的反应产物。一种示例性的可聚合组合物包括异构体的酯交换反应产物、碳酸二烯丙酯和至少一种多元醇。还提供了一种包括可聚合组合物的聚合物和一种包括可聚合组合物的光学制品。
• Composition for optical articles and optical articles made therewith
  申请人：PPG Industries Ohio, Inc.

  公开号：US10407540B2

  公开（公告）日：2019-09-10

  An exemplary polymerizable composition includes the reaction product of (a) diethyleneglycol bischloroformate; (b) allyl alcohol; (c) a cyclic polyol selected from the group consisting of a cycloaliphatic polyol having at least one secondary hydroxyl group, a heterocyclic polyol having primary and/or secondary hydroxyl groups, and mixtures thereof; (d) optionally, ethyleneglycol bischloroformate; and (e) optionally, at least one linear or branched aliphatic polyol having two to six hydroxyl groups. Another exemplary polymerizable composition includes the reaction product of (a) allyl alcohol; (b) a cyclic polyol selected from the group consisting of a cycloaliphatic polyol having at least one secondary hydroxyl group, a heterocyclic polyol having primary and/or secondary hydroxyl groups, and mixtures thereof; (c) ethyleneglycol bischloroformate; and (d) optionally, at least one linear or branched aliphatic polyol having two to six hydroxyl groups is also described. A reaction product, a polymerizate including the polymerizable composition, and an optical article including the polymerizable composition are also provided.

  一种示例性的可聚合组合物包括以下物质的反应产物：(a) 二乙二醇双氯甲酸酯；(b) 烯丙醇；(c) 环状多元醇，该多元醇选自由至少具有一个仲羟基的环脂族多元醇、具有伯羟基和/或仲羟基的杂环多元醇及其混合物组成的组；(d) 可选的乙二醇双氯甲酸酯；以及 (e) 可选的至少一种具有 2 至 6 个羟基的直链或支链脂肪族多元醇。另一种示例性可聚合组合物包括以下物质的反应产物：(a) 烯丙醇；(b) 环状多元醇，该多元醇选自由具有至少一个仲羟基的环脂族多元醇、具有伯羟基和/或仲羟基的杂环多元醇及其混合物组成的组；(c) 乙二醇双氯甲酸酯；以及 (d) 可选的至少一种具有二至六个羟基的直链或支链脂肪族多元醇。还提供了一种反应产物、一种包括可聚合组合物的聚合物和一种包括可聚合组合物的光学制品。