2,4-二甲基-6-丙基-1,3,5-三嗪 | 7559-34-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 中文名称: 2,4-二甲基-6-丙基-1,3,5-三嗪
• 英文名称: 2,4-dimethyl-6-propyl-s-triazine
• 英文别名: 2,4-Dimethyl-6-propyl-s-triazin；2,6-Dimethyl-4-n-propyl-1,3,5-triazin；2,4-Dimethyl-6-propyl-triazin；2,4-dimethyl-6-propyl-[1,3,5]triazine；2,4-Dimethyl-6-propyl-1,3,5-triazine
• CAS: 7559-34-4
• 化学式: C₈H₁₃N₃
• 分子量: 151.211
• InChiKey: QFRLJHQZIDNWGW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  11
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  38.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  2,4,6-三甲基-1,3,5-三嗪 、 溴乙烷 在 potassium hydride 作用下， 以 乙二醇二甲醚 为溶剂， 反应 48.0h， 以0.25 g的产率得到2,4-二甲基-6-丙基-1,3,5-三嗪
  参考文献：
  名称：

  Hydration with Mercuric Acetate and the Reduction with 9-BBN−H of 2-(1-Alkenyl)-4,6-dimethyl-s-triazines

  摘要：

  Oxymercuration-demercuration of a double bond in conjugation with the 4,6-dimethyl-s-triazin-2-yl substituent as in alkenes la,b gave anti-Markovnikov regioselectivity, which is explained by the electron-withdrawing nature of the triazinyl substituent. However, hydroboration of the conjugated alkenes with 9-BBN-H gave the corresponding alkanes 5a-c under normal workup conditions with or without oxidation. With time and without workup the hydroboration of 1b gave spectral evidence for the formation of intermediates 9-13 resulting from the migration of the 9-BBN moiety from the a-carbon to a ring nitrogen with concurrent formation of an exocyclic double bond to an a-carbon of the ring. Hydrolysis of the intermediates gave 5a-c. A possible mechanism involving successive allylic rearrangements is presented.

  DOI：

  10.1021/jo010784e

文献信息

• NEW TRIAZINE DERIVATIVE AND ULTRAVIOLET ABSORBER
  申请人：FUJIFILM Corporation

  公开号：US20140213704A1

  公开（公告）日：2014-07-31

  A compound represented by the following general formula (1), in the general formula (1), X 1a and X 1b represent a hydrogen atom or a substituent, Y 1 represents a substituent having a dissociative proton, Z 1a and Z 1b each independently represent heteroatom or a carbon atom, Q 1 represents an atomic group which is required to form an aromatic heterocycle together with Z 1a and Z 1b .

  一个由以下一般式（1）表示的化合物，在一般式（1）中，X1a和X1b代表氢原子或取代基，Y1代表具有可解离质子的取代基，Z1a和Z1b分别代表异原子或碳原子，Q1代表一个需要与Z1a和Z1b一起形成芳香杂环的原子团。
• MATERIALS FOR ELECTRONIC DEVICES
  申请人：MERCK PATENT GMBH

  公开号：US20150340627A1

  公开（公告）日：2015-11-26

  The present application relates to a compound of a formula (I), (II) or (III). The compound can be used in an electronic device, preferably an organic electronic device.

  本申请涉及公式(I)、(II)或(III)的化合物。该化合物可用于电子设备中，最好是有机电子设备。
• SYNTHETIC POLYMERS AND METHODS OF MAKING AND USING THE SAME
  申请人：Battelle Memorial Institute

  公开号：US20160257785A1

  公开（公告）日：2016-09-08

  Disclosed herein are monomer embodiments that can be used to make polymers, such as homopolymers, heteropolymers, and that can be used in particular embodiments to make sequence-defined polymers. Also disclosed herein are methods of making polymers using such monomer embodiments. Methods of using the polymers disclosed herein also are described.

  本文揭示了可用于制造聚合物的单体实施例，例如同聚物、异聚物，并且可以用于特定实施例中制造序列定义的聚合物。本文还揭示了使用此类单体实施例制造聚合物的方法。还描述了使用本文所揭示的聚合物的方法。
• Macrocycles, cobalt and iron complexes of same, and methods of making and using same
  申请人：The Research Foundation for The State University of New York

  公开号：US10960088B2

  公开（公告）日：2021-03-30

  Provided are macrocyclic compounds and iron or cobalt coordinated macrocyclic compounds. The compounds can be used as MRI contrast agents. Certain compounds are redox active and can be used to assess the biological redox status of a sample.

  本文提供了大环化合物和铁或钴配位大环化合物。这些化合物可用作核磁共振成像造影剂。某些化合物具有氧化还原活性，可用于评估样本的生物氧化还原状态。
• YANAGIYA KOSHIN; YASUMOTO MASAHIKO; KURABAYASHI MASAHIRO, TOKE KOGE SIKEHNSE XOKOKU, TOKUO KOGUO SNIKENSNO KOKOKU, J. NAT. CHEM. HA+
  作者：YANAGIYA KOSHIN、 YASUMOTO MASAHIKO、 KURABAYASHI MASAHIRO

  DOI：——

  日期：——