2,5-二氯-3-己基噻吩 | 817181-79-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 噻吩类
• 中文名称: 2,5-二氯-3-己基噻吩
• 英文名称: 2,5-Dichloro-3-hexylthiophene
• CAS: 817181-79-6
• 化学式: C₁₀H₁₄Cl₂S
• 分子量: 237.19
• InChiKey: PCILERIXBDAQNJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  13
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  28.2
• 氢给体数：
  0
• 氢受体数：
  1

文献信息

• METHOD FOR PRODUCING AROMATIC COMPOUND
  申请人：Sumitomo Chemical Company, Limited

  公开号：US20150322101A1

  公开（公告）日：2015-11-12

  A method is provided for producing an aromatic compound, including a step of mixing a compound represented by formula (A) and a compound represented by formula (B): in the presence of at least one phosphine compound selected from the group consisting of a phosphine represented by formula (C) and a phosphonium salt represented by formula (F): a base, a palladium compound, and an aprotic organic solvent.

  提供一种生产芳香化合物的方法，包括以下步骤：在至少一种磷化物化合物的存在下，将由化学式(A)表示的化合物与由化学式(B)表示的化合物混合；所述磷化物化合物选择自由化学式(C)表示的磷化物和由化学式(F)表示的磷酸盐；还包括碱、钯化合物和无水有机溶剂。
• METHOD FOR PRODUCTION OF CONJUGATED POLYMER
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP1997844A1

  公开（公告）日：2008-12-03

  A method for production of a conjugated polymer comprising contacting (A) an aromatic monomer having at least two boron-containing functional groups with an aromatic monomer having at least two reactive functional groups or (B) aromatic monomers having at least one boron-containing functional group and at least one reactive functional group with each other, both in an ether solvent in the presence of a palladium catalyst wherein a phosphine compound is coordinated to palladium, cesium carbonate and 1 to 100 moles of water per 1 mole of the boron-containing functional group of the above-mentioned aromatic monomer.

  一种生产共轭聚合物的方法，包括将(A)具有至少两个含硼官能团的芳香族单体与具有至少两个活性官能团的芳香族单体或(B)具有至少一个含硼官能团和至少一个活性官能团的芳香族单体相互接触、二者均在醚溶剂中，在钯催化剂（其中膦化合物与钯、碳酸铯配位）和每 1 摩尔上述芳香族单体的含硼官能团含有 1 至 100 摩尔水的条件下进行。
• METHOD FOR PRODUCING AROMATIC COMPOUND, AND PALLADIUM COMPLEX
  申请人：Sumitomo Chemical Company, Ltd

  公开号：EP3385270A1

  公开（公告）日：2018-10-10

  Provided is a catalyst used in the process for producing an aromatic compound giving high yield. A Palladium complex represented by the formula (D): wherein, X represents a chlorine atom or the like , A represents an alkyl group having a number of carbon atoms of 1 to 3, B represents an alkyl group having a number of carbon atoms of 4 to 20 or a cycloalkyl group having a number of carbon atoms of 5 to 10, R4 and R5 each independently represent a hydrogen atom, a fluorine atom, an alkoxy group having a number of carbon atoms of 1 to 20 or the like, and R6, R7 and R8 represent a hydrogen atom, an alkyl group having a number of carbon atoms of 1 to 20, an aryl group having a number of carbon atoms of 6 to 20 or a heteroaryl group having a number of carbon atoms of 4 to 20 or the like or the formula (D') : wherein, X, A, B and R4 to R8 are the same as defined above.

  本发明提供了一种用于高产率生产芳香化合物工艺的催化剂。 由式（D）表示的钯络合物： 其中，X 代表氯原子或类似物，A 代表碳原子数为 1 至 3 的烷基，B 代表碳原子数为 4 至 20 的烷基或碳原子数为 5 至 10 的环烷基，R4 和 R5 各自独立地代表氢原子、氟原子、碳原子数为 1 至 20 的烷氧基或类似物，以及 R6、R7 和 R8 分别代表氢原子、碳原子数为 1 至 20 的烷基、碳原子数为 6 至 20 的芳基或碳原子数为 4 至 20 的杂芳基或类似物。 式 (D') ： 其中，X、A、B 和 R4 至 R8 与上述定义相同。
• Process for producing aromatic compound, and palladium complex
  申请人：Sumitomo Chemical Company, Limited

  公开号：US11045796B2

  公开（公告）日：2021-06-29

  A process for producing an aromatic compound in high yield and a palladium complex are provided. The palladium complex is represented by formula (D) or formula (D′): In formula (D), X represents a chlorine atom, A represents an alkyl group having 1 to 3 carbon atoms, B represents an alkyl group having 4 to 20 carbon atoms or a cycloalkyl group having 5 to 10 carbon atoms, R4 and R5 each independently represent a hydrogen atom, a fluorine atom, or an alkoxy group having 1 to 20 carbon atoms, and R6, R7 and R8 represent a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms or a heteroaryl group having 4 to 20 carbon atoms. In formula (D′), X, A, B and R4 to R8 are the same as defined above.

  提供了一种高产率生产芳香化合物的工艺和一种钯络合物。钯络合物用式（D）或式（D′）表示： 在式(D)中，X代表氯原子，A代表具有1至3个碳原子的烷基，B代表具有4至20个碳原子的烷基或具有5至10个碳原子的环烷基，R4和R5各自独立地代表氢原子、氟原子或具有1至20个碳原子的烷氧基，R6、R7和R8代表氢原子、具有1至20个碳原子的烷基、具有6至20个碳原子的芳基或具有4至20个碳原子的杂芳基。 在式 (D′) 中，X、A、B 和 R4 至 R8 与上述定义相同。
• PROCESS FOR PREPARATION OF CONDUCTING POLYMERS
  申请人：BASF SE

  公开号：EP2203499A1

  公开（公告）日：2010-07-07