(7S,8R,7'R,8'S)-4,9,4',7'-tetrahydroxy-3,3'-dimethoxy-7,9'-epoxylignan 9-O-β-D-glucopyranoside | 1260540-40-6

分子结构分类

有机化合物 - 木脂素、新木脂素和相关化合物 - 木脂素苷

中文名称

——

中文别名

——

英文名称

(7S,8R,7'R,8'S)-4,9,4',7'-tetrahydroxy-3,3'-dimethoxy-7,9'-epoxylignan 9-O-β-D-glucopyranoside

英文别名

{(2S,3R,4S)-tetrahydro-4-[(R)-hydroxy(4-hydroxy-3-methoxyphenyl)methyl]-2-(4-hydroxy-3-methoxyphenyl)furan-3-yl}methyl β-D-glucopyranoside；(2R,3R,4S,5S,6R)-2-[[(2S,3R,4S)-4-[(R)-hydroxy-(4-hydroxy-3-methoxyphenyl)methyl]-2-(4-hydroxy-3-methoxyphenyl)oxolan-3-yl]methoxy]-6-(hydroxymethyl)oxane-3,4,5-triol

(7S,8R,7'R,8'S)-4,9,4',7'-tetrahydroxy-3,3'-dimethoxy-7,9'-epoxylignan 9-O-β-D-glucopyranoside化学式

CAS

1260540-40-6

化学式

C₂₆H₃₄O₁₂

mdl

——

分子量

538.549

InChiKey

FVMFBRPENVSJIZ-MSOGUVCCSA-N

BEILSTEIN

——

EINECS

——

计算性质

辛醇/水分配系数(LogP)：

-0.3
重原子数：

38
可旋转键数：

9
环数：

4.0
sp3杂化的碳原子比例：

0.54
拓扑面积：

188
氢给体数：

7
氢受体数：

12

上下游信息

下游产品

中文名称	英文名称	CAS号	化学式	分子量
——	(7S,8R,7'R,8'S)-4,4',9,7'-tetrahydroxy-3,3'-dimethoxy-7,9'-epoxylignan	1253588-18-9	C₂₀H₂₄O₇	376.406

反应信息

作为反应物：

描述：

(7S,8R,7'R,8'S)-4,9,4',7'-tetrahydroxy-3,3'-dimethoxy-7,9'-epoxylignan 9-O-β-D-glucopyranoside 在盐酸作用下，以水为溶剂，反应 5.0h，生成可得然胶

参考文献：

名称：

桂花中的四种新的木质素糖苷。变种 Mak木

摘要：

四个新木脂素tetrahydrofuranoid苷，（7小号，8 - [R，7' - [R，8'小号）-4,9,4'，7'-四羟基-3,3'-二甲氧基- 7,9'-epoxylignan 9- ö - β - d吡喃葡萄糖苷（2），（7 - [R，8小号，7'小号，8' - [R）-4,9,4'，7'-四羟基-3,3'-二甲氧基- 7,9'- epoxylignan 9- ø - β - d吡喃葡萄糖苷（3），（7 - [R，8小号，7' - [R，8'小号）-4,9,4'，9'-四羟基-3,3'-二甲氧基- 7 ，7'-环氧木脂素9-ø - β - d吡喃葡萄糖苷（4），和rel-（7 - [R，8小号，7'小号，8' - [R）-4,9,4'，9'-四羟基-3,3'-二甲氧基- 7 ，7'- epoxylignan 9- ø - β - d吡喃葡萄糖苷（5），和10木脂素甙，已知1和6

DOI：

10.1002/hlca.201000074

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