3-Trimethylstannyl-2-<(trimethylstannyl)methyl>propene | 86854-54-8

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机过渡后金属化合物
• 英文名称: 3-Trimethylstannyl-2-<(trimethylstannyl)methyl>propene
• 英文别名: 2-methylene-1,3-propanediylbis；1,3-bis(trimethylstannyl)-2-methylenepropane；2-Methylene-1,3-propanediylbis(trimethylstannane)；trimethyl-[2-(trimethylstannylmethyl)prop-2-enyl]stannane
• CAS: 86854-54-8
• 化学式: C₁₀H₂₄Sn₂
• 分子量: 381.721
• InChiKey: RLWRGLXLWYPBGH-UHFFFAOYSA-N

物化性质

• 沸点：
  95 °C

计算性质

• 辛醇/水分配系数(LogP)：
  4.22
• 重原子数：
  12
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  3-Trimethylstannyl-2-<(trimethylstannyl)methyl>propene 、 丁二酰氯 在 trans-benzyl(chloro)-bis(triphenylphosphine)palladium(II) 作用下， 生成 6-Methylene-1,4-cycloheptanedione
  参考文献：
  名称：

  [3 + n] Annulation Reactions by Means of 3-Trimethylstannyl-2-[(trimethylstannyl)methyl]propene, an Isobutene Dianion Synthetic Equivalent

  摘要：

  3- 三甲基锡-2-[(三甲基锡)甲基]丙烯中的两个碳-锡键与亲电体（二酰二氯或醛和二氧化碳）的逐步官能化为 [3 + n] 环化反应提供了一条很有前景的途径。

  DOI：

  10.1055/s-1991-26441
• 作为产物：
  描述：

  K2(trimethylenemethane) 、 三甲基氯化锡 以 正己烷 为溶剂， 以61%的产率得到3-Trimethylstannyl-2-<(trimethylstannyl)methyl>propene
  参考文献：
  名称：

  Trimethylenemethane complexes of ruthenium, osmium and rhodium via the compound CH₂C(CH₂SnMe₃)₂

  摘要：

  The compound CH2=C(CH2SnMe3)2 1 was readily made (61% yield) from K2(tmm) (tmm = trimethylenemethane) and SnMe3Cl. It serves as a new and efficient entry to tmm metal complexes. The arene complexes [{MCl2(arene)}2] (M = Ru or Os) reacted with 1 to give allylmetal complexes [MCI(CH2C(CH2SnMe3)CH2)(arene)] 2a-2e and sandwich-like compounds [M(tmm)(arene)] 3a-3e (M = Ru, arene = C6H6 a, C6Me6 b, or p-MeC6H4CHMe2 c; M = Os, arene = C6H6 d orp-MeC6H4CHMe2 e). The cymene complexes 3c and 39 can also be made using the combination CH2=C(CH2Cl)2-Mg-tetrahydrofuran as tmm source. Treatment of [{Rhl2(C5Me5)}2] with 1 produced [Rh(tmm)(C5Me5)] in high yield, and the carbonyl compounds [{MCl2(CO)3)2] (M = Ru or Os) afforded the tricarbonyl complexes [M(CO)3(tmm)] (M = Ru or Os) in good yields. X-Ray crystal structure determinations have been made for 2a, 3a and [Ru(CO)3(tmm)]. The data for the last two show the tmm ligand to be more firmly bonded in the arene complex.

  DOI：

  10.1039/dt9930002471

文献信息

• Primary aminomethylation of organometallic compounds via N,N-bis(trimethylsilyl)methylthiomethylamine
  作者：Luisa Fiocca、Mariella Fiorenza、Gianna Reginato、Alfredo Ricci、Pasquale Dembech、Giancarlo Seconi

  DOI：10.1016/0022-328x(88)89116-2

  日期：1988.3
• Knoerzer, Gabriele; Seyffer, Hermann; Pritzkow, Hans, Zeitschrift fur Naturforschung, B: Chemical Sciences, 1990, vol. 45, # 7, p. 985 - 988
  作者：Knoerzer, Gabriele、Seyffer, Hermann、Pritzkow, Hans、Siebert, Walter

  DOI：——

  日期：——
• Knoerzer, Gabriele; Seyffer, Hermann; Siebert, Walter, Zeitschrift fur Naturforschung, B: Chemical Sciences, 1990, vol. 45, # 8, p. 1136 - 1138
  作者：Knoerzer, Gabriele、Seyffer, Hermann、Siebert, Walter

  DOI：——

  日期：——
• Allylstannanes. Synthesis, structure, and reactions of 2-methylene-1,3-propanediylbis[trimethylstannane] and -[triphenylstannane]
  作者：Sosale Chandrasekhar、Stephan Latour、James D. Wuest、Boulos Zacharie

  DOI：10.1021/jo00169a042

  日期：1983.10
• KNORZER, GABRIELE;SEYFFER, HERMANN;PRITZKOW, HANS;SIEBERT, WALTER, Z. NATURFORSCH. B., 45,(1990) N, C. 985-988
  作者：KNORZER, GABRIELE、SEYFFER, HERMANN、PRITZKOW, HANS、SIEBERT, WALTER

  DOI：——

  日期：——