bis(trimethylsilyl)aminopentachlorodisilane | 18182-31-5

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: bis(trimethylsilyl)aminopentachlorodisilane
• 英文别名: [[[Dichloro(trichlorosilyl)silyl]-trimethylsilylamino]-dimethylsilyl]methane
• CAS: 18182-31-5
• 化学式: C₆H₁₈Cl₅NSi₄
• 分子量: 393.823
• InChiKey: VWQPOQJEWBCKRC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.11
• 重原子数：
  16
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  cyclopentadienyl iron(II) dicarbonyl dimer 、 bis(trimethylsilyl)aminopentachlorodisilane 以 正庚烷 为溶剂， 以76%的产率得到1-[(dicarbonyl)cyclopentadienyliron]-1,1,2,2-tetrachloro-2-(bistrimethylsilyl)aminodisilane
  参考文献：
  名称：

  Aminochlorodisilanes: Precursors to multifunctionalized disilane derivatives

  摘要：

  Multifunctionalized disilane derivatives containing silicon bonded to such elements as carbon, chlorine, hydrogen, nitrogen and iron were synthesized from bis(trimethylsilyl)aminopentachlorodisilane (1), 1,2-bis[bis(trimethylsilyl)amino]tetrachlorodisilane (2) or bis(phenyldimethylsilyl)aminopentachlorodisilane (3). 1, 2 and 3 were easily prepared from the reaction of Si2Cl6 with one or two equivalents of LiN(SiMe3)(2) or LiN(SiMe2Ph)(2), respectively. Partially hydrogenated chlorodisilanes were obtained from the corresponding aminodisilanes and dry HCl. (C) 1997 Elsevier Science S.A.

  DOI：

  10.1016/s0022-328x(97)00304-5

文献信息

• Aminochlorodisilanes: Precursors to multifunctionalized disilane derivatives
  作者：Harald Stüger、Paul Lassacher、Edwin Hengge

  DOI：10.1016/s0022-328x(97)00304-5

  日期：1997.12

  Multifunctionalized disilane derivatives containing silicon bonded to such elements as carbon, chlorine, hydrogen, nitrogen and iron were synthesized from bis(trimethylsilyl)aminopentachlorodisilane (1), 1,2-bis[bis(trimethylsilyl)amino]tetrachlorodisilane (2) or bis(phenyldimethylsilyl)aminopentachlorodisilane (3). 1, 2 and 3 were easily prepared from the reaction of Si2Cl6 with one or two equivalents of LiN(SiMe3)(2) or LiN(SiMe2Ph)(2), respectively. Partially hydrogenated chlorodisilanes were obtained from the corresponding aminodisilanes and dry HCl. (C) 1997 Elsevier Science S.A.