tri-n-dodecyltin hydride | 327622-63-9

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机过渡后金属化合物
• 英文名称: tri-n-dodecyltin hydride
• 英文别名: Tridodecylstannane；tridodecylstannane
• CAS: 327622-63-9
• 化学式: C₃₆H₇₆Sn
• 分子量: 627.709
• InChiKey: NGYPZSILTLRBCX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.98
• 重原子数：
  37
• 可旋转键数：
  33
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  硼烷 、 tris(dodecyl)(phenyl)stannane 以 四氢呋喃 为溶剂， 以78%的产率得到tri-n-dodecyltin hydride
  参考文献：
  名称：

  Transmetallations between aryltrialkyltins and borane: synthesis of arylboronic acids and organotin hydrides

  摘要：

  Aryltrialkyltin compounds react with borane in THF to give mixtures of trialkyltin hydrides and arylboranes, which on hydrolysis give arylboronic acid in high yields. The arylboronic acids are easily separated and obtained free of organotins. (C) 2000 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(00)00536-2

文献信息

• Transmetallations between aryltrialkyltins and borane: synthesis of arylboronic acids and organotin hydrides
  作者：M Faraoni

  DOI：10.1016/s0022-328x(00)00536-2

  日期：2000.11.3

  Aryltrialkyltin compounds react with borane in THF to give mixtures of trialkyltin hydrides and arylboranes, which on hydrolysis give arylboronic acid in high yields. The arylboronic acids are easily separated and obtained free of organotins. (C) 2000 Elsevier Science B.V. All rights reserved.