curium trichloride | 13537-20-7

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 锕系盐类
• 英文名称: curium trichloride
• 英文别名: Curium chloride；trichlorocurium
• CAS: 13537-20-7
• 化学式: Cl₃Cm
• 分子量: 353.429
• InChiKey: PTLGMSBPLOHNBD-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  2.07
• 重原子数：
  4
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  curium trichloride 在 氢氟酸 作用下， 以 水 为溶剂， 生成 curium trifluoride
  参考文献：
  名称：

  Raman spectra of selected transuranium trihalides in the solid state

  摘要：

  Raman spectral data have been obtained from a number of transuranium trihalides in the solid state. The Raman spectra of these actinide compounds are reported and compared to the published Raman spectra of isostructural compounds. Tentative symmetry assignments have been made for the observed Raman-active lattice vibrations based on nuclear site symmetry analysis of their respective crystal structures and comparisons to the symmetry assignments made for isostructural lanthanide compounds. The Raman spectral data obtained in this study represent a partial data base for the use of Raman spectroscopy for identifying the crystal structures exhibited by these and isostructural compounds.

  DOI：

  10.1063/1.455686
• 作为产物：
  描述：

  Cm-sesquioxide 在 盐酸 作用下， 生成 curium trichloride
  参考文献：
  名称：

  Raman spectra of selected transuranium trihalides in the solid state

  摘要：

  Raman spectral data have been obtained from a number of transuranium trihalides in the solid state. The Raman spectra of these actinide compounds are reported and compared to the published Raman spectra of isostructural compounds. Tentative symmetry assignments have been made for the observed Raman-active lattice vibrations based on nuclear site symmetry analysis of their respective crystal structures and comparisons to the symmetry assignments made for isostructural lanthanide compounds. The Raman spectral data obtained in this study represent a partial data base for the use of Raman spectroscopy for identifying the crystal structures exhibited by these and isostructural compounds.

  DOI：

  10.1063/1.455686

文献信息

• Crystal structure and lattice parameters of curium trichloride
  作者：J.C. Wallmann、J. Fuger、J.R. Peterson、J.L. Green

  DOI：10.1016/0022-1902(67)80013-7

  日期：1967.11

  CmCl3 has been found to exhibit the hexagonal UCl3 structure. Powder data from two samples give average lattice parameters a = 7·380 ± 0·006 Å and c = 4·186 ± 0·010 Å, where the error limits are the 95 per cent confidence interval calculated using the standard statistical method for the average of two independent determinations.

  已经发现CmCl 3具有六方UCL 3结构。来自两个样品的粉末数据给出平均晶格参数a = 7·380±0·006Å和c = 4·186±0·010Å，其中误差极限是使用标准统计学方法计算的95％置信区间。两个独立测定的平均值。
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Np: TrU.C, 6, page 129 - 147
  作者：

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Np: TrU.C, 8, page 153 - 157
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  日期：——
• Asprey; Keenan; Kruse, Inorganic Chemistry, 1964, vol. 3, # 8, p. 1137 - 1140
  作者：Asprey、Keenan、Kruse

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Np: TrU.C, 7, page 147 - 153
  作者：

  DOI：——

  日期：——