bis(methylsilyl) sulphide | 14396-23-7

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: bis(methylsilyl) sulphide
• 英文别名: Dimethylsilyl-sulfid；1,3-dimethyl-disilathiane；1,3-Dimethyl-disilathian；1,3-Dimethyldisilathiane；methyl(methylsilylsulfanyl)silane
• CAS: 14396-23-7
• 化学式: C₂H₁₀SSi₂
• 分子量: 122.338
• InChiKey: XEJKJGCMZUAGOZ-UHFFFAOYSA-N

物化性质

• 熔点：
  -120 °C
• 沸点：
  105 °C

计算性质

• 辛醇/水分配系数(LogP)：
  -0.02
• 重原子数：
  5
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  bis(methylsilyl) sulphide 、 氢碘酸 生成 methyl iodosilane 、 硫化氢
  参考文献：
  名称：

  117.甲基二硅氧烷和1：1：1-二甲基二甲硅烷基与硼和卤化氢的反应

  摘要：

  DOI：

  10.1039/jr9580000604
• 作为产物：
  描述：

  methyl iodosilane 在 mercury sulfide 作用下， 生成 bis(methylsilyl) sulphide
  参考文献：
  名称：

  Some Derivatives of Monoiodomonomethylsilane

  摘要：

  AbstractMono‐ and di‐iodomonomethylsilane, CH3SiH2I and CH3SiHI2, have been prepared by the reaction of monomethylsilane with hydrogen iodide in the presence of aluminium iodide. The monoiodo compound reacts with water to form the siloxan, (CH3SiH2)2O, with mercuric sulphide to form the silthian, (CH3SiH2)2S, and with silver cyanide to form the isocyanide, CH3SiH2NC, all of which have been characterised. The isocyanide does not react with nickel carbonyl and rapidly polymerises in the presence of boron trifluoride.

  DOI：

  10.1002/zaac.19562830109

文献信息

• Some Derivatives of Monoiodomonomethylsilane
  作者：Harry Emel�us、Mario Onyszchuk、Wilhelm Kuchen

  DOI：10.1002/zaac.19562830109

  日期：1956.1

  AbstractMono‐ and di‐iodomonomethylsilane, CH3SiH2I and CH3SiHI2, have been prepared by the reaction of monomethylsilane with hydrogen iodide in the presence of aluminium iodide. The monoiodo compound reacts with water to form the siloxan, (CH3SiH2)2O, with mercuric sulphide to form the silthian, (CH3SiH2)2S, and with silver cyanide to form the isocyanide, CH3SiH2NC, all of which have been characterised. The isocyanide does not react with nickel carbonyl and rapidly polymerises in the presence of boron trifluoride.
• 117. The reaction of methyldisiloxanes and 1 : 1-dimethyldisilthiane with boron and hydrogen halides
  作者：H. J. Emeléus、M. Onyszchuk

  DOI：10.1039/jr9580000604

  日期：——