(bicyclo[2.2.1]hept-5-en-2-yl)trichlorosilane | 14319-64-3

• 物质功能分类: 化学试剂 - 硅烷试剂
• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: (bicyclo[2.2.1]hept-5-en-2-yl)trichlorosilane
• 英文别名: 5-norbornenyl-2-trichlorosilane；5-(Bicycloheptenyl)trichlorosilane；[(1R,4R)-2-bicyclo[2.2.1]hept-5-enyl]-trichlorosilane
• CAS: 14319-64-3
• 化学式: C₇H₉Cl₃Si
• 分子量: 227.593
• InChiKey: RDAOXVBXDCANBV-JEAXJGTLSA-N

物化性质

• 熔点：
  <0°C
• 沸点：
  75 °C
• 密度：
  1.297
• 闪点：
  87°C

计算性质

• 辛醇/水分配系数(LogP)：
  3.06
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.714
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

安全信息

• TSCA：
  Yes
• 安全说明：
  S26,S36/37/39
• 危险类别码：
  R34,R36/37/38
• 危险品运输编号：
  UN 2987
• 海关编码：
  2931900090

反应信息

• 作为反应物：
  描述：

  2-噻吩基锂 、 (bicyclo[2.2.1]hept-5-en-2-yl)trichlorosilane 以 乙醚 为溶剂， 生成 (bicyclo[2.2.1]hept-5-en-2-yl)tri(2'-thienyl)silane 、 (bicyclo[2.2.1]hept-5-en-2-yl)tri(2'-thienyl)silane
  参考文献：
  名称：

  Functionalized polynorbornenes with organosilicon groups in the side chains. Synthesis and photophysical properties

  摘要：

  Using the method of metathesis polymerization carbon-chain homopolymers containing triNEurohenylsilyl, tritolylsilyl and trithienylsilyl groups in the side chains, as well as their copolymers with additional carbazole-containing units have been synthesized. Photophysical properties of the obtained compounds were investigated. All polymer products show an intense photoluminescence in the blue region of the spectrum. The largest quantum yield (61.4%) was shown by the copolymer with triphenylsilyl and carbazole side groups.

  DOI：

  10.1134/s1070363216010205

文献信息

• Functionalized polynorbornenes with organosilicon groups in the side chains. Synthesis and photophysical properties
  作者：Е. О. Platonova、Т. А. Kovylina、Е. V. Baranov、А. V. Arapova、L. N. Bochkarev

  DOI：10.1134/s1070363216010205

  日期：2016.1

  Using the method of metathesis polymerization carbon-chain homopolymers containing triNEurohenylsilyl, tritolylsilyl and trithienylsilyl groups in the side chains, as well as their copolymers with additional carbazole-containing units have been synthesized. Photophysical properties of the obtained compounds were investigated. All polymer products show an intense photoluminescence in the blue region of the spectrum. The largest quantum yield (61.4%) was shown by the copolymer with triphenylsilyl and carbazole side groups.