1,1,1-trifluoro-2,2,2-trimethyldisilane | 64809-82-1

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 1,1,1-trifluoro-2,2,2-trimethyldisilane
• 英文别名: trifluoro(trimethylsilyl)silane
• CAS: 64809-82-1
• 化学式: C₃H₉F₃Si₂
• 分子量: 158.271
• InChiKey: XIUVRANLWCUAIW-UHFFFAOYSA-N

物化性质

• 沸点：
  46.0±23.0 °C(Predicted)
• 密度：
  0.954±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.25
• 重原子数：
  8
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  1,1,1-trifluoro-2,2,2-trimethyldisilane 、 8-dimethylamino-1-naphthyllithium*(diethyl ether) 以 乙醚 为溶剂， 以77%的产率得到1-fluoro-1,1-bis(8-dimethylamino-1-naphthyl)-2,2,2-trimethyldisilane
  参考文献：
  名称：

  Synthesis, structure, and reactivity of disilanes containing one neutral [4+2]-coordinate silicon center

  摘要：

  [4+2]-Coordinate disilanes containing two 8-dimethylamino-1-naphthyl (8-Me2N-1-Np) groups on the same silicon atom, (8-Me2N-1-Np)(2)XSi-SiMe3, where X = F, OH, OEt. and H, are prepared. The X-ray structures of the two derivatives, X = F and OH, show that one of the coordinated dimethylamino groups is anti to the electronegative X group, while the other is anti to the trimethylsilyl group. The [4 + 2]-coordinate disilanes (X = F or OEt) are found to be thermally stable under these conditions such that the corresponding (4 + 1]-coordinate disilanes (8-Me2N-1-Np)XMeSi-SiMePh2 (X = F or OEt) readily undergo degradation. In the presence of Pd(PPh3)(4) as a catalyst, the [4 + 2]-coordinate disilane (X = F) undergoes degradation to generate naphthylsilane (8-Me2N-1-Np)-SiMe3, the reaction pathway being different from that of the [4 + 1]-coordinate disilane (X = F) which affords the fluorosilane, F-SiMePh2. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)01385-7
• 作为产物：
  描述：

  三甲基硅烷 在 difluorosilylene 作用下， 生成 1,1,1-trifluoro-2,2,2-trimethyldisilane
  参考文献：
  名称：

  Thompson,J.C.; Wright,A.P.G., Canadian Journal of Chemistry, 1979, vol. 57, p. 994 - 998

  摘要：

  DOI：

文献信息

• Organosilicon chemistry. Part XV. Thermal reactions of trifluoro(1,1,2,2-tetrafluoroethyl)silane and silicon tetrafluoride with methoxotrimethylsilane, hexamethyldisilazane, and trimethylsilanol
  作者：Robert N. Haszeldine、Anthony E. Tipping、Richard O'B. Watts

  DOI：10.1039/dt9750001431

  日期：——

  Trifluoro (1,1,2,2-tetrafiuoroethyl) silane reacts thermally with methoxotrimethylsilane, hexamethyldisilazane, or trimethylsilanol, possibly via co-ordination of the silicon atom of the SiF3 group with the nitrogen or oxygen atom of the other reactant, to give fluorotrimethylsilane and trimethoxo (1,1,2,2-tetrafluoroethyl) silane, tar, or polymeric material possibly the silsesquioxane (CHF2·CF2·Si·O1

  三氟（1,1,2,2- tetrafiuoroethyl）硅烷发生反应热与methoxotrimethylsilane，六甲基，三甲基硅烷醇或可能经由所述的SiF的硅原子的协调3与其它反应物的氮或氧原子团，得到氟三甲基硅烷和三甲氧基（1,1,2,2-四氟乙基）硅烷，焦油或高分子材料，分别是倍半硅氧烷（CHF 2 ·CF 2 ·Si·O 1.5）n。在相同条件下，四氟化硅与二硅氮烷或甲基氧硅烷相似地反应，分别得到氟代三甲基硅烷和1,1,1-三氟-3,3,3-三甲基二硅氮烷或氟代三甲基氧硅烷。
• Uhlig, Wolfram; Tzschach, Alfred, Zeitschrift fur Chemie, 1990, vol. 30, # 7, p. 254
  作者：Uhlig, Wolfram、Tzschach, Alfred

  DOI：——

  日期：——
• CMe3SiX3 and SiMe3SiX3 (X=H, F, Cl, Br, I): a combined ab initio and vibrational spectroscopic study
  作者：Robert Zink、Karl Hassler

  DOI：10.1016/s1386-1425(98)00189-9

  日期：1999.2

  The infrared and Raman vibrational spectra of the tert-butylsilanes CMe3SiX3 and disilanes SiMe3SiX3 (X = H, F, Cl, Br, I) have been measured and assigned with the help of normal coordinate analyses and potential energy distribution analyses employing ab initio optimized geometries and ab initio symmetry force constants. Scaled theoretical SiX and SiSi force constants are smaller than values estimated by extrapolation from spectroscopic force constants of related disilanes. The synthesis of the novel compound SiMe3SiI3 and the residual disilanes SiMe3SiX3 (X = H, F, Cl, Br) is described. (C) 1999 Elsevier Science B.V. All rights reserved.
• UHLIG, WOLFRAM;TZSCHACH, ALFRED, Z. CHEM., 30,(1990) N, C. 254
  作者：UHLIG, WOLFRAM、TZSCHACH, ALFRED

  DOI：——

  日期：——