Trimethyl-[2-[3-[4-[2-(2-trimethylsilylethynyl)thiophen-3-yl]phenyl]-5-[5-[5-(2-trimethylsilylethynyl)-4-[4-[2-(2-trimethylsilylethynyl)thiophen-3-yl]phenyl]thiophen-2-yl]pentyl]thiophen-2-yl]ethynyl]silane | 1104455-01-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 噻吩类
• 英文名称: Trimethyl-[2-[3-[4-[2-(2-trimethylsilylethynyl)thiophen-3-yl]phenyl]-5-[5-[5-(2-trimethylsilylethynyl)-4-[4-[2-(2-trimethylsilylethynyl)thiophen-3-yl]phenyl]thiophen-2-yl]pentyl]thiophen-2-yl]ethynyl]silane
• 英文别名: trimethyl-[2-[3-[4-[2-(2-trimethylsilylethynyl)thiophen-3-yl]phenyl]-5-[5-[5-(2-trimethylsilylethynyl)-4-[4-[2-(2-trimethylsilylethynyl)thiophen-3-yl]phenyl]thiophen-2-yl]pentyl]thiophen-2-yl]ethynyl]silane
• CAS: 1104455-01-7
• 化学式: C₅₃H₆₀S₄Si₄
• 分子量: 937.665
• InChiKey: PYQBTJXVYCLVLT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  16.47
• 重原子数：
  61
• 可旋转键数：
  18
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.32
• 拓扑面积：
  113
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  1,4-bis[2-(trimethylsilylethynyl)-3-thienyl]benzene 、 1,5-二碘戊烷 在 正丁基锂 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 以74%的产率得到Trimethyl-[2-[3-[4-[2-(2-trimethylsilylethynyl)thiophen-3-yl]phenyl]-5-[5-[5-(2-trimethylsilylethynyl)-4-[4-[2-(2-trimethylsilylethynyl)thiophen-3-yl]phenyl]thiophen-2-yl]pentyl]thiophen-2-yl]ethynyl]silane
  参考文献：
  名称：

  Preparations of bis[2-(2-arylethynyl)-3-thienyl]arenes and bis[2-{2-(trimethylsilyl)ethynyl}-3-thienyl]arenes

  摘要：

  4,4'-Bis[2-(2-phenylethynyl)-3-thienyl]biphenyl, 4,4'-bis[2-[2-(trimethylsilyl)ethynyl}-3-thienyl]biphenyl and their congeners were prepared and their properties were studied. Extension of pi-system through the central benzene ring was suggested by UV-vis spectra. Connection of two 1,4-bis[2-{2-(trimethylsilyl)ethynyl}-3-thienyl]benzene units was exemplified. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2008.10.088

文献信息

• Preparations of bis[2-(2-arylethynyl)-3-thienyl]arenes and bis[2-{2-(trimethylsilyl)ethynyl}-3-thienyl]arenes
  作者：Kozo Toyota、Kazuyuki Okada、Hiroshi Katsuta、Noboru Morita

  DOI：10.1016/j.tet.2008.10.088

  日期：2009.1

  4,4'-Bis[2-(2-phenylethynyl)-3-thienyl]biphenyl, 4,4'-bis[2-[2-(trimethylsilyl)ethynyl}-3-thienyl]biphenyl and their congeners were prepared and their properties were studied. Extension of pi-system through the central benzene ring was suggested by UV-vis spectra. Connection of two 1,4-bis[2-2-(trimethylsilyl)ethynyl}-3-thienyl]benzene units was exemplified. (C) 2008 Elsevier Ltd. All rights reserved.