环丙醇碳酸盐 | 149674-61-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机碳酸及其衍生物
• 中文名称: 环丙醇碳酸盐
• 英文名称: Dicyclopropanol carbonate
• 英文别名: carbonic acid;cyclopropanol
• CAS: 149674-61-3
• 化学式: C7H14O5
• 分子量: 178.18
• InChiKey: XTHPGWUTKYMOJN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.5
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  98
• 氢给体数：
  4
• 氢受体数：
  5

文献信息

• Environment-friendly liquid fuel and production process thereof
  申请人：Beijing Jinjiao Biomass Chemical Industry Co., Ltd

  公开号：EP2664608A1

  公开（公告）日：2013-11-20

  The present invention discloses a liquid fuel and production process thereof. The liquid fuel comprises dialkyl carbonates with the structural formula of wherein R and R' are same or different, and R and R' are selected from the group consisting of C1-C8 linear chain alkyl, C3-C8 branched chain alkyl, C3-C8 naphthene base and alkyl containing furan ring. The process of the production of the liquid fuel comprises the steps of: performing a cycloaddition reaction between 2-methyl tetrahydrofuran and carbon dioxide to produce a cyclic carbonate, then performing an ester exchange reaction between the cyclic carbonate and monohydric alcohol to produce the dialkyl carbonate. The liquid fuel produced by the present invention is clean, safe and biodegradable; it is compatible with advantages of conventional fossil-based liquid fuels and biological liquid fuels and has a wide range of applications. The process provides a new way for industrial production of the dialkyl carbonate and efficient and comprehensive utilization of biomass resources.

  本发明揭示了液体燃料及其生产工艺。该液体燃料包括具有结构式的二烷基碳酸酯，其中R和R'相同或不同，且R和R'选自由C1-C8直链烷基、C3-C8支链烷基、C3-C8萘基和含有呋喃环的烷基组成的群。生产该液体燃料的工艺包括以下步骤：对2-甲基四氢呋喃和二氧化碳进行环加成反应，生成环碳酸酯，然后对环碳酸酯和一元醇进行酯交换反应，生成二烷基碳酸酯。本发明生产的液体燃料洁净、安全、可生物降解；它兼具传统基于化石的液体燃料和生物液体燃料的优点，并具有广泛的应用范围。该工艺为工业生产二烷基碳酸酯提供了一种新途径，实现了生物质资源的高效综合利用。
• ENVIRONMENTAL-FRIENDLY LIQUID FUEL AND PRODUCTION PROCESS THEREOF
  申请人：Beijing Jinjiao Biomass chemical industry Co., Ltd

  公开号：US20130305595A1

  公开（公告）日：2013-11-21

  The present invention discloses a liquid fuel and production process thereof, the liquid fuel comprises dialkyl carbonates with the structural formula of wherein R and R′ are same or different, and R and R′ are selected from the group consisting of C1-C8 linear chain alkyl, C3-C8 branched chain alkyl, C3-C8 naphthene base and alkyl containing furan ring. The process of the production of the liquid fuel comprises the steps of: performing a cycloaddition reaction between 2-methyl tetrahydrofuran produced by hydrogenation from furfural which is a biomass derivative and carbon dioxide to produce a cyclic carbonate (i.e. 1,4-pentanediol carbonate), then performing an ester exchange reaction between the cyclic carbonate and monohydric alcohol to produce the dialkyl carbonate. The liquid fuel produced by the present invention is clean, safe and biodegradable; it is compatible with advantages of conventional fossil-based liquid fuels and biological liquid fuels and with a wide range of applications, the process provides a new way for industrial production of the dialkyl carbonate and efficient and comprehensive utilization of biomass resources, the economic and social benefit is remarkable. The present invention discloses a liquid fuel and production process thereof, the liquid fuel comprises dialkyl carbonates with the structural formula of wherein R and R′ are same or different, and R and R′ are selected from the group consisting of C1-C8 linear chain alkyl, C3-C8 branched chain alkyl, C3-C8 naphthene base and alkyl containing furan ring. The process of the production of the liquid fuel comprises the steps of: performing a cycloaddition reaction between 2-methyl tetrahydrofuran produced by hydrogenation from furfural which is a biomass derivative and carbon dioxide to produce a cyclic carbonate (i.e. 1,4-pentanediol carbonate), then performing an ester exchange reaction between the cyclic carbonate and monohydric alcohol to produce the dialkyl carbonate. The liquid fuel produced is clean, safe and biodegradable, and the process provides a new way for industrial production of the dialkyl carbonate with remarkable economic and social benefit.

  本发明披露了一种液体燃料及其生产工艺，该液体燃料包括具有结构式的二烷基碳酸酯其中R和R'相同或不同，R和R'被选自由C1-C8线性链烷基，C3-C8支链烷基，C3-C8萘基和含有呋喃环的烷基组成的群体。该液体燃料的生产过程包括以下步骤：通过将生物质衍生物糠醛氢化产生的2-甲基四氢呋喃和二氧化碳进行环加成反应以产生环状碳酸酯（即1,4-戊二醇碳酸酯），然后通过将环状碳酸酯和单元醇进行酯交换反应以产生二烷基碳酸酯。本发明生产的液体燃料洁净、安全、可生物降解，具有常规化石燃料和生物燃料的优点，适用范围广泛，该工艺为工业生产二烷基碳酸酯和高效综合利用生物质资源提供了新的途径，具有显著的经济和社会效益。
• US9045707B2
  申请人：——

  公开号：US9045707B2

  公开（公告）日：2015-06-02