chlorodimethyl(tetradecyl)silane | 59551-80-3

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: chlorodimethyl(tetradecyl)silane
• 英文别名: chlorodimethyltetradecylsilane；Tetradecyl-dimethyl-chlor-silan；Chloro(dimethyl)tetradecylsilane；chloro-dimethyl-tetradecylsilane
• CAS: 59551-80-3
• 化学式: C₁₆H₃₅ClSi
• 分子量: 290.992
• InChiKey: IOXIXDQBMHCXBF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.13
• 重原子数：
  18
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  chlorodimethyl(tetradecyl)silane 在 水 、 苯胺 作用下， 生成 Tetradecyl-dimethyl-silanol
  参考文献：
  名称：

  关于烷基和氧杂烷基二甲基硅烷醇的制备的注意事项

  摘要：

  描述了一系列烷基和（单，​​二和多）氧杂烷基二甲基硅烷醇的制备。通过预先通过硅胶柱过滤，这些化合物在储存时的稳定性大大提高。

  DOI：

  10.1002/hlca.19760590302
• 作为产物：
  描述：

  溴代十四烷 在 四氯化碳 、 magnesium 、 palladium dichloride 作用下， 以 四氢呋喃 为溶剂， 反应 3.25h， 生成 chlorodimethyl(tetradecyl)silane
  参考文献：
  名称：

  Trialkylsilylethynyl-substituted triphenylenes and hexabenzocoronenes: highly soluble liquid crystalline materials and their hole transport abilities

  摘要：

  Four triphenylene (TP) and four hexa-peri-hexabenzocoronene (HBC) derivatives with trialkylsilylethynyl groups were prepared and characterized by differential scanning calorimetry, polarizing optical microscopy, and X-ray diffraction measurements. All compounds were highly soluble in less-polar organic solvents and exhibited a columnar phase, Col(h) or Col(r) for the TPs, and Col(h) for the HBCs. The hole transport ability in the HBCs' columnar phase, 0.4-1.5x10(-3) cm(2) V-1 s(-1) at 40-180 degrees C, and its temperature dependence were determined by the time-of-flight method using a solution technique. (C) 2015 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2015.05.071

文献信息

• Monofunctional (Dimethylamino)silane as Silylating Agent
  作者：Katalin Szabó、Ngoc Le Ha、Philippe Schneider、Peter Zeltner、Ervin sz. Kováts

  DOI：10.1002/hlca.19840670813

  日期：1984.12.19

  The reaction of triorganyl(dimethylamino)silanes with surface-hydrated silicon dioxide has been studied. These silylating agents are easy to prepare from the corresponding chloro or bromosilanes with dimethylamine. The resulting products are thermally stable and relatively volatile. Reaction with surface-hydrated silicon-dioxide preparations at 150–250°C for 170 h yields a dense grafted layer. However

  研究了三有机基（二甲基氨基）硅烷与表面水合二氧化硅的反应。这些甲硅烷基化剂易于由相应的氯硅烷或溴硅烷与二甲胺制备。所得产物是热稳定的和相对挥发性的。在150–250°C下与表面水合二氧化硅制备物反应170 h，得到致密的接枝层。然而，对于具有强极性取代基的（二甲基氨基）硅烷而言，为了获得最大的覆盖率，似乎有必要对表面改性的二氧化硅进行重新处理。
• Lamellar Assembly of Conical Molecules Possessing a Fullerene Apex in Crystals and Liquid Crystals
  作者：Yu-Wu Zhong、Yutaka Matsuo、Eiichi Nakamura

  DOI：10.1021/ja068780k

  日期：2007.3.1

  Shuttlecock molecules made of fullerene and five side chains that have previously been shown to self-assemble into a polar columnar structure are now made into a lamellar structure in crystals and liquid crystals. The molecular design is such that the conical molecules C-60((C6H4CCSiMe2CnH2n+1)-C-n)(5)Me form crystals when the silicon substituent is a methyl group and that they form smectic liquid crystals when one of them is a long hydrocarbon chain. The fullerene groups in each layer interact with each other very strongly, suggesting that such lamellar structures may be useful for organic electronics applications.
• Trialkylsilylethynyl-substituted triphenylenes and hexabenzocoronenes: highly soluble liquid crystalline materials and their hole transport abilities
  作者：Takuji Hirose、Yutaro Miyazaki、Mizuki Watabe、Sho Akimoto、Tatsuya Tachikawa、Koichi Kodama、Mikio Yasutake

  DOI：10.1016/j.tet.2015.05.071

  日期：2015.7

  Four triphenylene (TP) and four hexa-peri-hexabenzocoronene (HBC) derivatives with trialkylsilylethynyl groups were prepared and characterized by differential scanning calorimetry, polarizing optical microscopy, and X-ray diffraction measurements. All compounds were highly soluble in less-polar organic solvents and exhibited a columnar phase, Col(h) or Col(r) for the TPs, and Col(h) for the HBCs. The hole transport ability in the HBCs' columnar phase, 0.4-1.5x10(-3) cm(2) V-1 s(-1) at 40-180 degrees C, and its temperature dependence were determined by the time-of-flight method using a solution technique. (C) 2015 Elsevier Ltd. All rights reserved.
• Note on the Preparation of Alkyl- and Oxaälkyl-dimethylsilanols
  作者：László Boksányi、Olivier Liardon、Ervin sz. Kováts

  DOI：10.1002/hlca.19760590302

  日期：1976.4.21

  The preparation of a series of alkyl- and (mono-, di- and poly-) oxaälkyl-dimethylsilanols is described. The stability of these compounds on storage is considerably increased by previous filtration through a silica gel column.

  描述了一系列烷基和（单，​​二和多）氧杂烷基二甲基硅烷醇的制备。通过预先通过硅胶柱过滤，这些化合物在储存时的稳定性大大提高。