piperidinium fluoride | 63812-16-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 哌啶类
• 英文名称: piperidinium fluoride
• 英文别名: piperidine * HF；Piperidin-1-ium;fluoride
• CAS: 63812-16-8
• 化学式: C₅H₁₂N*F
• 分子量: 105.155
• InChiKey: JBQNHQIURDYDFL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.91
• 重原子数：
  7
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  12
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  piperidinium fluoride 在 水 、 silica gel 作用下， 以94%的产率得到bis[piperidinium] hexafluorosilicate
  参考文献：
  名称：

  Ammonium hexafluorosilicate salts

  摘要：

  The preparation and characterization of the ammonium hexafluorosilicate salts, 2[R](+) [SiF6](2-) (where R = piperidinium (2), methylammonium (3), quinolinium (4), acridinium (5), 2,2,6,6-tetramethylpiperidinium (6), and propylammonium (7)) is described.The salts were prepared from the reaction of the corresponding alkylammonium fluoride with silica gel. The compounds were characterized by NMR, IR, mass spectrometry and in the case of 1 (piperidinium fluoride), 2-4 by X-ray crystallography. Compounds 1-3 crystallize in the orthorhombic crystal system (space groups Iba2, Fdd2, and Pnnm, respectively), with Z = 8, 14, and 4, respectively. Compound 4 crystallizes in the triclinic space group P-1, with Z = 2. Compounds 1-4 exhibit hydrogen bonding. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-1139(02)00046-5
• 作为产物：
  描述：

  哌啶 在 氢氟酸 作用下， 反应 2.0h， 生成 piperidinium fluoride
  参考文献：
  名称：

  Ammonium hexafluorosilicate salts

  摘要：

  The preparation and characterization of the ammonium hexafluorosilicate salts, 2[R](+) [SiF6](2-) (where R = piperidinium (2), methylammonium (3), quinolinium (4), acridinium (5), 2,2,6,6-tetramethylpiperidinium (6), and propylammonium (7)) is described.The salts were prepared from the reaction of the corresponding alkylammonium fluoride with silica gel. The compounds were characterized by NMR, IR, mass spectrometry and in the case of 1 (piperidinium fluoride), 2-4 by X-ray crystallography. Compounds 1-3 crystallize in the orthorhombic crystal system (space groups Iba2, Fdd2, and Pnnm, respectively), with Z = 8, 14, and 4, respectively. Compound 4 crystallizes in the triclinic space group P-1, with Z = 2. Compounds 1-4 exhibit hydrogen bonding. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-1139(02)00046-5

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: F: PerFHalOrg.2, 1.3.4, page 137 - 166
  作者：

  DOI：——

  日期：——
• 512. Perfluoroalkyl derivatives of sulphur. Part VI. Perfluoroalkanesulphonic acids CF₃·[CF₂]_n·SO₃H (n= 1—7)
  作者：T. Gramstad、R. N. Haszeldine

  DOI：10.1039/jr9570002640

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: F: PerFHalOrg.2, 1.3.3, page 120 - 137
  作者：

  DOI：——

  日期：——
• Titskii, G. D.; Mitchenko, E. S., Journal of Organic Chemistry USSR (English Translation), 1988, vol. 24, # 10, p. 1949 - 1954
  作者：Titskii, G. D.、Mitchenko, E. S.

  DOI：——

  日期：——
• Rodionov, Peter P.; Osina, Ol'Ga I.; Platonov, Vyacheslav E., Bulletin de la Societe Chimique de France, 1986, # 6, p. 986 - 993
  作者：Rodionov, Peter P.、Osina, Ol'Ga I.、Platonov, Vyacheslav E.、Yakobson, Georg G.

  DOI：——

  日期：——