1,1-diethoxy-1-sila-2-oxa-4-azacycloheptan-3-one | 62305-46-8

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 1,1-diethoxy-1-sila-2-oxa-4-azacycloheptan-3-one
• 英文别名: 2,2-diethoxy-[1,6,2]oxazasilepan-7-one；2,2-Diethoxy-1,6,2-oxazasilepan-7-one
• CAS: 62305-46-8
• 化学式: C₈H₁₇NO₄Si
• 分子量: 219.313
• InChiKey: IYSQFEDBYSRGJR-UHFFFAOYSA-N

物化性质

• 密度：
  1.08±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.13
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.88
• 拓扑面积：
  56.8
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  3-氨基丙基三乙氧基硅烷 、 trimethylsilyl diethylcarbamate 以97%的产率得到1,1-diethoxy-1-sila-2-oxa-4-azacycloheptan-3-one
  参考文献：
  名称：

  Application of aminopropyltriethoxysilane and N-[2-(aminoethyl)-N-3-(trimethoxysilyl)propyl]amine to the synthesis of linear and heterocyclic compounds

  摘要：

  Reaction of 3-aminopropyltriethoxysilane and N-[2-(aminoethyl)-N-3-(trimethoxysilyl)propyl]-amine and their derivatives with diethylcarbamic acid trimethylsilyl ether and trimetisilylisocyanate proceeds through the stage of formation of intermediate products which under conditions of the synthesis undergo intramolecular (in the case of formation O-silylcarbamates) and intermolecular (in the case of the formation of carbamide trimethylsilyl derivatives) desilylation leading to the cyclic and linear products respectively.

  DOI：

  10.1134/s1070363209100119

文献信息

• Sheludyakov,V.D. et al., Journal of general chemistry of the USSR, 1976, vol. 46, p. 2589 - 2594
  作者：Sheludyakov,V.D. et al.

  DOI：——

  日期：——
• Application of aminopropyltriethoxysilane and N-[2-(aminoethyl)-N-3-(trimethoxysilyl)propyl]amine to the synthesis of linear and heterocyclic compounds
  作者：A. D. Kirilin、L. O. Belova、A. V. Gavrilova、E. A. Korobova

  DOI：10.1134/s1070363209100119

  日期：2009.10

  Reaction of 3-aminopropyltriethoxysilane and N-[2-(aminoethyl)-N-3-(trimethoxysilyl)propyl]-amine and their derivatives with diethylcarbamic acid trimethylsilyl ether and trimetisilylisocyanate proceeds through the stage of formation of intermediate products which under conditions of the synthesis undergo intramolecular (in the case of formation O-silylcarbamates) and intermolecular (in the case of the formation of carbamide trimethylsilyl derivatives) desilylation leading to the cyclic and linear products respectively.