Bis-<5.5-dimethyl-2-thioxo-1.3.2-dioxaphosphorinanyl-(2)>-sulfid | 4090-54-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机二硫代磷酸及其衍生物
• 英文名称: Bis-<5.5-dimethyl-2-thioxo-1.3.2-dioxaphosphorinanyl-(2)>-sulfid
• 英文别名: 2-[(5,5-Dimethyl-2-sulfanylidene-1,3,2lambda5-dioxaphosphinan-2-yl)sulfanyl]-5,5-dimethyl-2-sulfanylidene-1,3,2lambda5-dioxaphosphinane；2-[(5,5-dimethyl-2-sulfanylidene-1,3,2λ5-dioxaphosphinan-2-yl)sulfanyl]-5,5-dimethyl-2-sulfanylidene-1,3,2λ5-dioxaphosphinane
• CAS: 4090-54-4
• 化学式: C₁₀H₂₀O₄P₂S₃
• 分子量: 362.412
• InChiKey: QJOBHAXUGXPRIU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  19
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  126
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  sodium 2,2-dimethylpropylene dithiophosphate 在 2-bromo-1-methyl-pyridinium iodide 作用下， 以 甲醇 为溶剂， 反应 1.5h， 以77%的产率得到Bis-<5.5-dimethyl-2-thioxo-1.3.2-dioxaphosphorinanyl-(2)>-sulfid
  参考文献：
  名称：

  A Facile Method for the Preparation of Cyclic Trithiopyrophosphate

  摘要：

  Cyclic trithiopyrophosphates can be prepared from the reaction of alkali metal dithiophosphates or pyridinium dithiophosphates with 2-bromo-1-methylpyridinium iodide in high yields under mild and efficient conditions.

  DOI：

  10.1080/00397919108021580

文献信息

• Lopusinski, Andrzej; Luczak, Lech; Brzezinska, Ewa, Phosphorus and Sulfur and the Related Elements, 1987, vol. 31, p. 101 - 108
  作者：Lopusinski, Andrzej、Luczak, Lech、Brzezinska, Ewa

  DOI：——

  日期：——
• [EN] PHOSPHORUS-SULFUR FR ADDITIVES AND POLYMER SYSTEMS CONTAINING SAME<br/>[FR] ADDITIFS IGNIFUGEANTS À BASE DE PHOSPHORE-SOUFRE ET SYSTÈMES POLYMÉRIQUES CONTENANT CEUX-CI
  申请人：DOW GLOBAL TECHNOLOGIES INC

  公开号：WO2009035881A2

  公开（公告）日：2009-03-19

  Certain phosphorus- sulfur compounds are effective in reducing the LOI of combustible organic polymers and in providing better FR characteristics to the polymers as determined by other standardized tests. The phosphorus-sulfur compounds are sulfur-bridged, metal-bridged or in the form of salts such a ammonium, sulfonium or phosphonium salts.
• A Facile Method for the Preparation of Cyclic Trithiopyrophosphate
  作者：Jae Eun Cho、Dong Young Oh

  DOI：10.1080/00397919108021580

  日期：1991.9

  Cyclic trithiopyrophosphates can be prepared from the reaction of alkali metal dithiophosphates or pyridinium dithiophosphates with 2-bromo-1-methylpyridinium iodide in high yields under mild and efficient conditions.