(E)-3-chloro-2-perfluoronutanesulfinyl-1-ethoxyprop-1-ene | 1184977-59-0

• 分子结构分类: 有机化合物 - 有机硫化合物 - 亚砜
• 英文名称: (E)-3-chloro-2-perfluoronutanesulfinyl-1-ethoxyprop-1-ene
• 英文别名: 1-[(E)-3-chloro-1-ethoxyprop-1-en-2-yl]sulfinyl-1,1,2,2,3,3,4,4,4-nonafluorobutane
• CAS: 1184977-59-0
• 化学式: C₉H₈ClF₉O₂S
• 分子量: 386.666
• InChiKey: DKFKBOOGYLBVIC-SNAWJCMRSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  22
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  45.5
• 氢给体数：
  0
• 氢受体数：
  12

反应信息

• 作为产物：
  描述：

  1,2-丙二烯,1-乙氧基- 、 nonafluorobutanesulfinyl chloride 以78%的产率得到(E)-3-chloro-2-perfluoronutanesulfinyl-1-ethoxyprop-1-ene
  参考文献：
  名称：

  The addition of perfluoroalkanesulfinyl chlorides to alkoxyallenes

  摘要：

  The addition reaction of perfluoroalkanesulfinyl chlorides to alkoxyallenes was achieved under mild conditions. Two kinds of perfluoroalkyl alkenyl sulfoxides, beta-alkoxyvinyl perfluoroalkyl sulfoxides and alpha-perfluoroalkanesulfinyl enones or enals, were obtained selectively depending on the structure of alkoxyallenes. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jfluchem.2008.12.007

文献信息

• The addition of perfluoroalkanesulfinyl chlorides to alkoxyallenes
  作者：Ling-Jun Chen、Jin-Tao Liu

  DOI：10.1016/j.jfluchem.2008.12.007

  日期：2009.3

  The addition reaction of perfluoroalkanesulfinyl chlorides to alkoxyallenes was achieved under mild conditions. Two kinds of perfluoroalkyl alkenyl sulfoxides, beta-alkoxyvinyl perfluoroalkyl sulfoxides and alpha-perfluoroalkanesulfinyl enones or enals, were obtained selectively depending on the structure of alkoxyallenes. (C) 2008 Elsevier B.V. All rights reserved.