carbon trioxide | 16518-45-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机碳酸及其衍生物
• 英文名称: carbon trioxide
• CAS: 16518-45-9
• 化学式: CO₃
• 分子量: 60.0092
• InChiKey: DPFFXSPEODLYOH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.1
• 重原子数：
  4
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  19.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  carbonate radical anion 以 neat (no solvent) 为溶剂， 生成 carbon trioxide
  参考文献：
  名称：

  Photodetachment Cross Sections for CO3− and Its First Hydrate

  摘要：

  The cross sections for the aeronomically important processes CO3−+hν→CO3+e− and CO3−·H2O+hν→CO3· H2O+e− are measured at a pressure of 2 torr. The ions are detected in a differentially pumped quadrupole mass spectrometer. The photodetachment threshold energy is 1.8 eV for CO3− and 2.1 eV for CO3− · H2O. Their solar photodetachment rates are, respectively, 1.4 and 1.1 sec−1 relative to the O− rate of 1.44 sec−1.

  DOI：

  10.1063/1.1678131

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: C: MVol.C4, 4.4.2, page 46 - 46
  作者：

  DOI：——

  日期：——
• Reactions of molecularly adsorbed oxygen on metals: Carbon monoxide and sulfur dioxide reactions with oxygen on Ag(110)
  作者：Armand J. Capote、Jeffrey T. Roberts、Robert J. Madix

  DOI：10.1016/0039-6028(89)90074-5

  日期：1989.3
• Photodetachment Cross Sections for CO3− and Its First Hydrate
  作者：J. A. Burt

  DOI：10.1063/1.1678131

  日期：1972.12

  The cross sections for the aeronomically important processes CO3−+hν→CO3+e− and CO3−·H2O+hν→CO3· H2O+e− are measured at a pressure of 2 torr. The ions are detected in a differentially pumped quadrupole mass spectrometer. The photodetachment threshold energy is 1.8 eV for CO3− and 2.1 eV for CO3− · H2O. Their solar photodetachment rates are, respectively, 1.4 and 1.1 sec−1 relative to the O− rate of 1.44 sec−1.