4-[Bis(4-hydroxyphenyl)-(6-oxobenzo[c][2,1]benzoxaphosphinin-6-yl)methyl]phenol | 862458-86-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 三苯基化合物
• 英文名称: 4-[Bis(4-hydroxyphenyl)-(6-oxobenzo[c][2,1]benzoxaphosphinin-6-yl)methyl]phenol
• CAS: 862458-86-4
• 化学式: C₃₁H₂₃O₅P
• 分子量: 506.494
• InChiKey: KLDIUQAZOTUPOK-UHFFFAOYSA-N

物化性质

• 熔点：
  295 °C(Solv: ethanol (64-17-5))
• 沸点：
  789.2±70.0 °C(Predicted)
• 密度：
  1.45±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.1
• 重原子数：
  37
• 可旋转键数：
  4
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.03
• 拓扑面积：
  87
• 氢给体数：
  3
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  4-[Bis(4-hydroxyphenyl)-(6-oxobenzo[c][2,1]benzoxaphosphinin-6-yl)methyl]phenol 、 丙烯酰氯 在 potassium carbonate 作用下， 以 二甲基亚砜 为溶剂， 反应 20.0h， 生成
  参考文献：
  名称：

  无卤阻燃型不饱和聚酯组合物、聚酯制品、其 制法与应用

  摘要：

  本发明公开了一种含磷丙烯酸酯，其具有下式所示结构：本发明还公开了一种无卤阻燃型不饱和聚酯组合物，其包含所述含磷丙烯酸酯。本发明还公开了所述含磷丙烯酸酯、无卤阻燃型不饱和聚酯组合物及其固化物的制备方法和应用。本发明的无卤阻燃型不饱和聚酯组合物及其固化物制备工艺简单，操作方法简便，可控制性好，易于实施。本发明的无卤阻燃性不饱和聚酯组合物及其固化物在保持良好的热力学性能的同时，还具备优异的阻燃性能，有着良好的应用前景，使用范围广泛。

  公开号：

  CN111777642B
• 作为产物：
  描述：

  4,4'-二羟基二苯甲酮 、 苯酚 、 9,10-二氢-9-氧杂-10-磷杂菲-10-氧化物 在 溶剂黄146 作用下， 反应 24.0h， 生成 4-[Bis(4-hydroxyphenyl)-(6-oxobenzo[c][2,1]benzoxaphosphinin-6-yl)methyl]phenol
  参考文献：
  名称：

  无卤阻燃型不饱和聚酯组合物、聚酯制品、其 制法与应用

  摘要：

  本发明公开了一种含磷丙烯酸酯，其具有下式所示结构：本发明还公开了一种无卤阻燃型不饱和聚酯组合物，其包含所述含磷丙烯酸酯。本发明还公开了所述含磷丙烯酸酯、无卤阻燃型不饱和聚酯组合物及其固化物的制备方法和应用。本发明的无卤阻燃型不饱和聚酯组合物及其固化物制备工艺简单，操作方法简便，可控制性好，易于实施。本发明的无卤阻燃性不饱和聚酯组合物及其固化物在保持良好的热力学性能的同时，还具备优异的阻燃性能，有着良好的应用前景，使用范围广泛。

  公开号：

  CN111777642B

文献信息

• Phosphorus-containing compounds and their preparing process and use
  申请人：Chang Chun Plastics Co., Ltd.

  公开号：US08222441B2

  公开（公告）日：2012-07-17

  A series of novel phosphorus-containing compounds having the following formula are disclosed: wherein R1-R12, A, B, D, X, and Y are as defined in the specification. A process for the preparation of the compound of formula (1), a curing agent, and a flame resistant epoxy resin and a preparation process thereof are also provided.

  披露了一系列具有以下公式的含磷新化合物： 其中 R1-R12、A、B、D、X和Y的定义如说明书所述。 还提供了公式（1）化合物的制备方法、固化剂以及耐火焰环氧树脂及其制备过程。
• FLAME-RETARDANT POLYPHENYLENE ETHER RESIN COMPOSITION
  申请人：Shengyi Technology Co., Ltd.

  公开号：EP3564316A1

  公开（公告）日：2019-11-06

  The present invention relates to a flame-retardant polyphenylene ether resin composition, comprising, by weight percent: (A) 10-45% of a phosphorus-containing polyphenylene ether resin with a number-average molecular weight of 1000-6000; (B) 10-50% of an epoxy resin composition; (C) 10-50% of a cyanate ester resin; and (D) 10-30% of a soluble halogen flame retardant. The present invention adopts a phosphorus-containing polyphenylene ether resin with a low molecular weight that, when used in combination with an epoxy resin, a cyanate ester, and the like, improves the compatibility of the system and reduces a phase separation area of the system, and increases the adhesive force of a plate and enhances the toughness of the plate. The present invention adopts a soluble halogen flame retardant to further enhance the homogeneity of the resin system, and provides better uniformity, increased adhesion, and a lower dielectric constant and dielectric loss of the plate.

  本发明涉及一种阻燃聚苯醚树脂组合物，按重量百分比计包括：(A)10-45%的数均分子量为1000-6000的含磷聚苯醚树脂；(B)10-50%的环氧树脂组合物；(C)10-50%的氰酸酯树脂；以及(D)10-30%的可溶性卤素阻燃剂。本发明采用了一种低分子量的含磷聚苯醚树脂，该树脂与环氧树脂、氰酸酯等配合使用时，可提高体系的相容性，减少体系的相分离面积，增加板材的粘合力，提高板材的韧性。本发明采用可溶性卤素阻燃剂，进一步提高了树脂体系的均匀性，使板材具有更好的均匀性、更强的附着力、更低的介电常数和介电损耗。
• Novel phosphorus-containing compounds and their preparing process and use
  申请人：Chang Chun Plastics Co., Ltd.

  公开号：EP2116549B1

  公开（公告）日：2015-08-05
• PHOSPHORUS CONTAINING BENZOXAZINE-BASED MONOMER, POLYMER THEREOF, ELECTRODE FOR FUEL CELL INCLUDING THE POLYMER, ELECTROLYTE MEMBRANE FOR FUEL CELL INCLUDING THE POLYMER, AND FUEL CELL USING THE ELECTRODE
  申请人：CHOI Seongwoo

  公开号：US20090123812A1

  公开（公告）日：2009-05-14

  A phosphorus containing monomer, a polymer thereof, an electrode for a fuel cell including the polymer, an electrolyte membrane for a fuel cell including the polymer, and a fuel cell including the electrode. The phosphorus containing monomer is represented by Formula 1: Group A is represented by:
• METHOD FOR MECHANICALLY STABILIZING NITROGEN-CONTAINING POLYMERS
  申请人：Gronwald Oliver

  公开号：US20120231365A1

  公开（公告）日：2012-09-13

  A method for the production of mechanically stabilized polyazole polymers, comprising the following steps: a) providing a membrane comprising i.) polyazoles with at least one amino group in a repeating unit except the ones obtainable by reacting aromatic and/or heteroaromatic diaminocarboxylic acids, ii.) at least one strong acid and iii.) at least one stabilizing reagent, the total content of stabilizing reagents in the membrane being within the range of from 0.01 to 30% by weight, b) performing the stabilization reaction in the membrane, immediately or in a subsequent processing step of the membrane, c) if appropriate, additionally doping the membrane obtained in accordance with step b) with a strong acid or concentrating the present strong acid further by removal of present water, wherein the stabilizing agent comprises at least one oxazine-based compound. The polyazole polymer membranes thus obtainable are in particular characterized by a high conductivity and a very good mechanical stability. Therefore, they are in particular suited for applications in fuel cells.