2,8-di-tert-butyldibenzofuran | 133373-14-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并呋喃
• 英文名称: 2,8-di-tert-butyldibenzofuran
• 英文别名: 3,6-di-t-butyldibenzofuran；2,8-Di-tert-butyldibenzo[b,d]furan；2,8-ditert-butyldibenzofuran
• CAS: 133373-14-5
• 化学式: C₂₀H₂₄O
• 分子量: 280.41
• InChiKey: SJGXOBRPLZLBFY-UHFFFAOYSA-N

物化性质

• 沸点：
  382.3±11.0 °C(Predicted)
• 密度：
  1.023±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7
• 重原子数：
  21
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  13.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  5,5'-di-tert-butyl-2,2'-dihydroxybiphenyl 生成 2,8-di-tert-butyldibenzofuran
  参考文献：
  名称：

  YAMATO, TAKEHIKO;HIDESHIMA, CHIEKO;PRAKASH, SURYA G. K.;OLAH, GEORGE A., J. ORG. CHEM., 56,(1991) N, C. 3192-3194

  摘要：

  DOI：

文献信息

• Compounds for organic electroluminescence device
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US11342512B2

  公开（公告）日：2022-05-24

  A compound represented by the following formula (1), wherein one or more pairs among R12 and R13, R13 and R14, R14 and R15, R16 and R17, R17 and R18, and R18 and R19 independently form a ring represented by the following formula (2A) or a ring represented by the following formula (2B), or do not form a ring represented by the following formula (2A) and do not form a ring represented by the following formula (2B); and one of R12 to R28 is bonded with L2.

  下式(1)代表的化合物，其中 R12 和 R13、R13 和 R14、R14 和 R15、R16 和 R17、R17 和 R18 以及 R18 和 R19 中的一对或多对独立地形成下式(2A)代表的环或下式(2B)代表的环，或不形成下式(2A)代表的环，也不形成下式(2B)代表的环；以及 R12 至 R28 中的一个与 L2 键合。
• Solid superacid catalyzed organic synthesis. 6. Perfluorinated resinsufonic acid (Nafion-H) catalyzed ring closure reaction of 2,2'-dihydroxybiphenyls. A preparative route to dibenzofurans
  作者：Takehiko Yamato、Chieko Hideshima、G. K. Surya Prakash、George A. Olah

  DOI：10.1021/jo00009a051

  日期：1991.4
• New Dibenzofuran Formation from the Reactions of 1-Cyclohexenyloxydibutylboranes with 2,3-Dichloro-5,6-dicyano-p-benzoquinone (DDQ)
  作者：Kiyoshi Tanemura、Koji Yamaguchi、Hideo Arai、Tsuneo Suzuki、Takaaki Horaguchi

  DOI：10.3987/com-95-7199

  日期：——

  Cyclohexenyloxydibutylboranes, generated in situ, reacted with 2,3-dichloro-5,6-dicyano-p-benzoquinone (DDQ) to give dibenzofurans.
• YAMATO, TAKEHIKO;HIDESHIMA, CHIEKO;PRAKASH, SURYA G. K.;OLAH, GEORGE A., J. ORG. CHEM., 56,(1991) N, C. 3192-3194
  作者：YAMATO, TAKEHIKO、HIDESHIMA, CHIEKO、PRAKASH, SURYA G. K.、OLAH, GEORGE A.

  DOI：——

  日期：——
• NOVEL COMPOUND AND ORGANIC ELECTROLUMINESCENCE DEVICE
  申请人：IDEMITSU KOSAN CO.,LTD.

  公开号：US20210066599A1

  公开（公告）日：2021-03-04

  A compound represented by the following formula (1), wherein one or more pairs among R 12 and R 13 , R 13 and R 14 , R 14 and R 15 , R 16 and R 17 , R 17 and R 18 , and R 18 and R 19 independently form a ring represented by the following formula (2A) or a ring represented by the following formula (2B), or do not form a ring represented by the following formula (2A) and do not form a ring represented by the following formula (2B); and one of R 12 to R 28 is bonded with L 2 .