(4-chloro-6-methoxy-[1,3,5]triazin-2-yl)-dimethyl-amine | 13882-55-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: (4-chloro-6-methoxy-[1,3,5]triazin-2-yl)-dimethyl-amine
• 英文别名: 4-chloro-6-methoxy-N,N-dimethyl-1,3,5-triazin-2-amine；2-Chlor-4-dimethylamino-6-methoxy-1,3,5-triazin；6-Chlor-4-dimethylamino-2-methoxy-1,3,5-triazin
• CAS: 13882-55-8
• 化学式: C₆H₉ClN₄O
• 分子量: 188.617
• InChiKey: GPZJPODLTKLYNX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  12
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  51.1
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  (4-chloro-6-methoxy-[1,3,5]triazin-2-yl)-dimethyl-amine 在 氯化亚砜 、 sodium methylate 作用下， 生成 6-Chloroethylamino-4-dimethylamino-2-methoxy-sym-triazine
  参考文献：
  名称：

  Condensation of ethanolamine with chloro-sym-triazines

  摘要：

  DOI：

  10.1007/bf00482504
• 作为产物：
  描述：

  N-(4-Dimethylamino-6-methoxy-[1,3,5]triazin-2-yl)-hydroxylamine 生成 (4-chloro-6-methoxy-[1,3,5]triazin-2-yl)-dimethyl-amine
  参考文献：
  名称：

  MOSKALENKO, G. G.;SEDOVA, V. F.;AXMETOVA, V. R.;ODINOKOV, V. N.;MAMAEV, V+, XIMIYA GETEROTSIKL. SOED.,(1990) N, S. 657-661

  摘要：

  DOI：

文献信息

• Synthese heterocyclischer α-oxo-essigsaeureester mit einem neuen acylanionaequivalent
  作者：Adrian Waldner

  DOI：10.1016/s0040-4039(00)85398-8

  日期：1986.1
• Studies of the New Herbicide KIH-6127. Part II. Synthesis and Herbicidal Activity of 6-Acyl Pyrimidin-2-yl Salicylates and Analogues against Barnyard Grass
  作者：Masatoshi Tamaru、Takayoshi Takehi、Naoshi Masuyama、Ryo Hanai

  DOI：10.1002/(sici)1096-9063(199608)47:4<327::aid-ps432>3.0.co;2-u

  日期：1996.8

  The method reported previously (Part I) was employed to prepare a variety of novel 6-acylsalicylates as key intermediates. 6-Acylpyrimidin-2-yl salicylates (2-acyl-6-[(4,6-disubstituted pyrimidin-2-yl)oxy]benzoate derivatives: Type 1), the closely related phthalide compounds (3-alkyl-7-[(4,6-dimethoxypyrimidin-2-yl)oxy]phthalide derivatives: Type 2) and the ketal derivatives of 2-acyl-6-[(4,6-dimethoxypyrimidin-2-yl)oxy]benzoates (Type 3) were synthesized and their herbicidal activities measured. Methyl 2-acetyl-6-[(4,6-dimethoxypyrimidin-2-yl)oxy]benzoate gave excellent control of barnyard grass with a promising profile as a prototype rice herbicide.
• Manganese dioxide oxidation of hydroxyamino-sym-triazines
  作者：V. F. Sedova、O. P. Shkurko

  DOI：10.1007/bf00534476

  日期：1993.5
• Synthesis of 2- and 4-Nitropyrimidines and 2-Nitro-sym-triazines by ozonization of hydroxyamino and nitroso derivatives
  作者：G. G. Moskalenko、V. F. Sedova、V. R. Akhmetova、V. N. Odinokov、V. P. Mamaev

  DOI：10.1007/bf00487433

  日期：1990.5
• s-Triazine derivatives. 3. Investigation of the reaction of chloromethoxy-s-triazines with CH acids
  作者：G. M. Vakhatova、L. N. Yakhontov

  DOI：10.1007/bf00507257

  日期：1981.2