4'-hydroxybiphenyl-4-yl 4-(undec-10-enoyloxy)benzoate | 753458-21-8

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 英文名称: 4'-hydroxybiphenyl-4-yl 4-(undec-10-enoyloxy)benzoate
• 英文别名: [4-(4-Hydroxyphenyl)phenyl] 4-undec-10-enoyloxybenzoate；[4-(4-hydroxyphenyl)phenyl] 4-undec-10-enoyloxybenzoate
• CAS: 753458-21-8
• 化学式: C₃₀H₃₂O₅
• 分子量: 472.581
• InChiKey: AXVSLZXJKCOISE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.5
• 重原子数：
  35
• 可旋转键数：
  15
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  72.8
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  4'-hydroxybiphenyl-4-yl 4-(undec-10-enoyloxy)benzoate 在 吡啶 、 氯化亚砜 作用下， 以 四氢呋喃 、 氯仿 为溶剂， 生成 4'-(6-chloro-6-oxohexanoyloxy)biphenyl-4-yl 4-(undec-10-enoyloxy)benzoate
  参考文献：
  名称：

  含末端全氟化碳链的侧链液晶聚合物和取向弹性体的合成与表征

  摘要：

  通过与聚（甲基氢）硅氧烷，环氧单体2-（烯丙氧基甲基）环氧乙烷的一步氢化硅烷化反应，将几种含有环氧基和介晶组分的新型手性侧链液晶（LC）聚硅氧烷树脂接枝共聚，并进行手性氟化液晶单体4'-（4-（烯丙氧基）苯甲酰氧基）联苯-4-基6-（全氟辛酰氧基）六氢呋喃[ 3,2-b ]呋喃-3-基己二酸酯和4'-（4-（十一月10 -烯酰氧基）苯甲酰氧基）联苯-4-基6-（全氟辛酰氧基）六氢呋喃[ 3,2-b]己基-3-呋喃基己酸酯。使用4,4'-二氨基二苯基甲烷在中间相状态下在磁场下固化合成的环氧树脂，以获得交联的取向弹性体。单体，树脂和液晶弹性体（LCE）的化学结构，LC特性和表面形态通过多种实验技术进行表征，例如FTIR，1 H NMR，EA，TGA，DSC，POM和X-射线测量。合成树脂和相应的取向弹性体的介晶性能受到末端全氟化碳链组分的有效影响。树脂显示手性向列相和手性近晶C相（小号C*），以及

  DOI：

  10.1016/j.polymer.2011.09.002
• 作为产物：
  描述：

  10-十一碳烯基氯酸 在 吡啶 、 氯化亚砜 作用下， 以 四氢呋喃 、 N,N-二甲基甲酰胺 为溶剂， 生成 4'-hydroxybiphenyl-4-yl 4-(undec-10-enoyloxy)benzoate
  参考文献：
  名称：

  New Liquid-Crystalline Elastomers: 1. Synthesis, Structure, and Phase Behavior of a Series of Mesogenic Crosslinking Agents Containing Reactive Bifunctional Groups

  摘要：

  The synthesis of eight mesogenic crosslinking agents (1c-8c) containing reactive bifunctional groups is described. The chemical structures were characterized by Fourier transform infrared (FTIR) and 1H nuclear magnetic resonance (NMR) spectra. The mesomorphism was investigated by differential scanning calorimetry (DSC) and polarizing optical microscopy (POM). The compounds 1c, 2c, 3c, 5c, 6c, and 8c showed an enantiotropic nematic phase. In addition, 5c exhibited a smectic A (SmA) phase on cooling; 4c exhibited a smectic C (SmC) phase, a SmA phase, and a nematic phase and a monotropic a smectic B (SmB) phase on cooling. 7c revealed an SmA phase and a nematic phase and a monotropic SmC phase on cooling.

  DOI：

  10.1080/15421406.2010.526561

文献信息

• Synthesis and characterization of side-chain liquid crystalline polymers and oriented elastomers containing terminal perfluorocarbon chains
  作者：Fan-Bao Meng、Xiao-Dong Zhang、Xiao-Zhi He、He Lu、Yue Ma、Hui-Li Han、Bao-Yan Zhang

  DOI：10.1016/j.polymer.2011.09.002

  日期：2011.10

  Several novel chiral side-chain liquid crystalline (LC) polysiloxane resins containing epoxy groups and mesogenic components have been graft copolymerized by a one-step hydrosilylation reaction with poly(methylhydrogeno)siloxane, an epoxy monomer 2-(allyloxymethyl)oxirane, and chiral fluorinated liquid-crystalline monomers 4′-(4-(allyloxy)benzoyloxy)biphenyl-4-yl 6-(perfluorooctanoyloxy)hexahydrofuro[3

  通过与聚（甲基氢）硅氧烷，环氧单体2-（烯丙氧基甲基）环氧乙烷的一步氢化硅烷化反应，将几种含有环氧基和介晶组分的新型手性侧链液晶（LC）聚硅氧烷树脂接枝共聚，并进行手性氟化液晶单体4'-（4-（烯丙氧基）苯甲酰氧基）联苯-4-基6-（全氟辛酰氧基）六氢呋喃[ 3,2-b ]呋喃-3-基己二酸酯和4'-（4-（十一月10 -烯酰氧基）苯甲酰氧基）联苯-4-基6-（全氟辛酰氧基）六氢呋喃[ 3,2-b]己基-3-呋喃基己酸酯。使用4,4'-二氨基二苯基甲烷在中间相状态下在磁场下固化合成的环氧树脂，以获得交联的取向弹性体。单体，树脂和液晶弹性体（LCE）的化学结构，LC特性和表面形态通过多种实验技术进行表征，例如FTIR，1 H NMR，EA，TGA，DSC，POM和X-射线测量。合成树脂和相应的取向弹性体的介晶性能受到末端全氟化碳链组分的有效影响。树脂显示手性向列相和手性近晶C相（小号C*），以及
• New Liquid-Crystalline Elastomers: 1. Synthesis, Structure, and Phase Behavior of a Series of Mesogenic Crosslinking Agents Containing Reactive Bifunctional Groups
  作者：Xiao-Xu Xu、Zhe Hong、Fei Liu

  DOI：10.1080/15421406.2010.526561

  日期：2010.12.1

  The synthesis of eight mesogenic crosslinking agents (1c-8c) containing reactive bifunctional groups is described. The chemical structures were characterized by Fourier transform infrared (FTIR) and 1H nuclear magnetic resonance (NMR) spectra. The mesomorphism was investigated by differential scanning calorimetry (DSC) and polarizing optical microscopy (POM). The compounds 1c, 2c, 3c, 5c, 6c, and 8c showed an enantiotropic nematic phase. In addition, 5c exhibited a smectic A (SmA) phase on cooling; 4c exhibited a smectic C (SmC) phase, a SmA phase, and a nematic phase and a monotropic a smectic B (SmB) phase on cooling. 7c revealed an SmA phase and a nematic phase and a monotropic SmC phase on cooling.