[2-Butyl-3-(trimethylsilylmethylidene)hept-1-enyl]-trimethylsilane | 1007364-39-7

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: [2-Butyl-3-(trimethylsilylmethylidene)hept-1-enyl]-trimethylsilane
• CAS: 1007364-39-7
• 化学式: C₁₈H₃₈Si₂
• 分子量: 310.671
• InChiKey: HFIWAHPMQHWSAC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.97
• 重原子数：
  20
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  环辛炔 、 1-三甲基硅烷-1-己炔 在 溴丁基-镁 、 二氯二茂锆 、 盐酸 、 水 作用下， 以 四氢呋喃 为溶剂， 以56%的产率得到[2-(1-cycloocten-1-yl)-hex-1-en-1-yl]-(trimethyl)silane
  参考文献：
  名称：

  Cyclomagnesation of cycloalkynes with the use of RMgR’ catalyzed by zirconium complexes

  摘要：

  The intermolecular cyclomagnesation of cycloalkynes and joint cyclomagnesation of cycloalkynes and disubstituted acetylenes was carried out by treating with RMgR' (R, R' = Et, Bu, H1g) in the presence of Cp2ZrCl2 as a catalyst. As a result new unsaturated bi-and tricyclic organomagnesium compounds were obtained in high yields.

  DOI：

  10.1134/s1070428009110037

文献信息

• Cyclomagnesation of cycloalkynes with the use of RMgR’ catalyzed by zirconium complexes
  作者：V. A. D’yakonov、A. A. Makarov、U. M. Dzhemilev

  DOI：10.1134/s1070428009110037

  日期：2009.11

  The intermolecular cyclomagnesation of cycloalkynes and joint cyclomagnesation of cycloalkynes and disubstituted acetylenes was carried out by treating with RMgR' (R, R' = Et, Bu, H1g) in the presence of Cp2ZrCl2 as a catalyst. As a result new unsaturated bi-and tricyclic organomagnesium compounds were obtained in high yields.