1,1-dioctadecyl-piperidinium; chloride | 61550-95-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 哌啶类
• 英文名称: 1,1-dioctadecyl-piperidinium; chloride
• 英文别名: 1,1-Dioctadecyl-piperidinium; Chlorid；1,1-Dioctadecylpiperidin-1-ium chloride；1,1-dioctadecylpiperidin-1-ium;chloride
• CAS: 61550-95-6
• 化学式: C₄₁H₈₄N*Cl
• 分子量: 626.578
• InChiKey: VIVCEUZLQDOOQZ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  11.51
• 重原子数：
  43
• 可旋转键数：
  34
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  1,5-二氯戊烷 、 双十八烷基胺 在 potassium carbonate 、 正丁醇 作用下， 生成 1,1-dioctadecyl-piperidinium; chloride
  参考文献：
  名称：

  Reactions of Long-chain Amines. IV. Preparation of N-Alkylpyrrolidines, N,N-Dialkylpyrrolidinium Chlorides and N,N-Dialkylpiperidinium Chlorides¹

  摘要：

  DOI：

  10.1021/ja01607a082

文献信息

• PROCESS FOR THE PRODUCTION OF TRIARYL ORGANOBORATES
  申请人：Covestro Deutschland AG

  公开号：US20190276479A1

  公开（公告）日：2019-09-12

  The invention relates to a process for preparing triaryl organoborates proceeding from alkyl or cycloalkyl boronates in the presence of an n-valent cation 1/n K n+ and to the use of these substances as co-initiator in photopolymer formulations.

  这项发明涉及一种制备三芳基有机硼酸盐的过程，该过程从烷基或环烷基硼酸盐在n价阳离子1/n Kn+存在下进行，并将这些物质用作光聚合物配方中的协同引发剂。
• METHOD FOR PRODUCING TRIARYLORGANOBORATES
  申请人：Covestro Deutschland AG

  公开号：US20190263838A1

  公开（公告）日：2019-08-29

  The invention relates to a process for preparing triaryl organoborates proceeding from organoboronic esters in the presence of an n-valent cation 1/n K n+ , comprising the anhydrous workup of the reaction mixture and the use of the triaryl organoborates obtained as co-initiator in photopolymer formulations, holographic media and holograms.

  该发明涉及一种从有机硼酸酯出发制备三芳基有机硼酸酯的方法，该方法在n价阳离子1/n Kn+存在下进行，包括对反应混合物进行无水处理和使用所得的三芳基有机硼酸酯作为光聚合物配方、全息介质和全息图中的共同引发剂。
• PHOTOPOLYMER FORMULATION FOR PRODUCTION OF HOLOGRAPHIC MEDIA COMPRISING BORATES WITH LOW TG
  申请人：COVESTRO DEUTSCHLAND AG

  公开号：US20160252808A1

  公开（公告）日：2016-09-01

  The invention relates to a photopolymer formulation comprising a component reactive toward isocyanates, a polyisocyanate component, a writing monomer and a photoinitiator containing at least one dye and a coinitiator, characterized in that the coinitiator contains at least one substance of the formula (Ia) The invention further provides a process for preparing the specific coinitiators and the coinitiators obtainable by this process, and additionally a process for producing a holographic medium using the specific coinitiators, and a holographic medium obtainable using the inventive photopolymer formulation. The invention further relates to a laminate structure comprising an inventive holographic medium and likewise specific borates suitable as coinitiators.

  本发明涉及一种光聚合物配方，包括一种对异氰酸反应的组分、一种聚异氰酸酯组分、一种写入单体和一种光引发剂，其中光引发剂含有至少一种染料和一个共引发剂，其特征在于该共引发剂含有至少一种式(Ia)的物质。本发明还提供了制备特定共引发剂和可获得此过程的共引发剂的方法，以及使用特定共引发剂制备全息介质的方法，以及使用本发明的光聚合物配方获得的全息介质。本发明还涉及一种层压结构，包括一种创新的全息介质，以及同样适用作共引发剂的特定硼酸。
• Photopolymer formulation for production of holographic media comprising borates with low TG
  申请人：Covestro Deutschland AG

  公开号：US10001703B2

  公开（公告）日：2018-06-19

  The invention relates to a photopolymer formulation comprising a component reactive toward isocyanates, a polyisocyanate component, a writing monomer and a photoinitiator containing at least one dye and a coinitiator, characterized in that the coinitiator contains at least one substance of the formula (Ia) The invention further provides a process for preparing the specific coinitiators and the coinitiators obtainable by this process, and additionally a process for producing a holographic medium using the specific coinitiators, and a holographic medium obtainable using the inventive photopolymer formulation. The invention further relates to a laminate structure comprising an inventive holographic medium and likewise specific borates suitable as coinitiators.

  本发明涉及一种光聚合物配方，包括对异氰酸酯具有反应性的组分、多异氰酸酯组分、书写单体和含有至少一种染料和助引发剂的光引发剂，其特征在于助引发剂含有至少一种式 (Ia) 的物质 本发明进一步提供了制备特定引发剂的工艺和通过该工艺获得的引发剂，以及使用特定引发剂生产全息介质的工艺和使用本发明光聚合物配方获得的全息介质。本发明还涉及一种层压结构，包括本发明的全息介质和同样适合作为引发剂的特定硼酸盐。
• Process for the production of triaryl organoborates
  申请人：Covestro Deutschland AG

  公开号：US11078218B2

  公开（公告）日：2021-08-03

  Provided herein is a process for preparing triaryl organoborates proceeding from alkyl or cycloalkyl boronates in the presence of an n-valent cation 1/n Kn+ to obtain organoborates of the formula 1/n Kn+R34B−—R1 (IV), where one equivalent of organoboronic ester of the formula B—R1(OR2)(OR3) (I) is initially charged together with 1/n equivalents of salt Kn+ nX− (II) and 3 equivalents of metal M in a solvent or a solvent mixture, 3 equivalents of a haloaromatic R4—Y (III) are added, and optionally a second organic solvent water is added and the compound 1/n Kn+ R24B−—R1 (IV) is separated off with the organic phase, and to the use of these substances as co-initiator in photopolymer formulations.

  本发明提供了一种制备三芳基有机硼酸盐的工艺，该工艺由烷基或环烷基硼酸盐在正价阳离子 1/n Kn+ 的存在下进行，得到式 1/n Kn+R34B--R1 (IV)的有机硼酸盐，其中一当量的式 B-R1(OR2)(OR3)(I)的有机硼酸酯最初与 1/n 当量的盐 Kn+ nX- (II) 和 3 当量的金属 M 一起充入溶剂或溶剂混合物中、加入 3 个当量的卤代芳香族化合物 R4-Y (III)，并可选择加入第二种有机溶剂水，然后将化合物 1/n Kn+ R24B--R1 (IV) 与有机相分离，并将这些物质用作光聚合物配方中的共引发剂。