palladium(II) bis(di-i-butyldithiocarbamate) | 52613-84-0

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: palladium(II) bis(di-i-butyldithiocarbamate)
• 英文别名: palladium(II) bis(diisobutyldithiocarbamate)；bis(diisobutyldithiocabamato)palladium(II)；N,N-bis(2-methylpropyl)carbamodithioate;palladium(2+)
• CAS: 52613-84-0
• 化学式: C₁₈H₃₆N₂PdS₄
• 分子量: 515.181
• InChiKey: KPDYTMBIXSQQQU-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  4.86
• 重原子数：
  25
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  72.7
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  di-i-butylammonium di-i-butyldithiocarbamate 、 palladium dichloride 以 1,2-二氯乙烷 为溶剂， 生成 palladium(II) bis(di-i-butyldithiocarbamate)
  参考文献：
  名称：

  摘要：

  The standard molar enthalpies of formation of crystalline dialkyldithiocarbamates chelates, [Pd(S2CNR2)(2)], with R=C2H5, n-C3H7, n-C4H9 and i-C4H9, were determined through reaction-solution calorimetry in acetone, at 298.15 K. From the standard molar enthalpies of formation of the gaseous chelates, the homolytic (172.4+/-3.8, 182.5+/-3.2, 150.9+/-3.1 and 162.6+/-3.1 kJ mol(-1)) and heterolytic (745.0+/-3.8, 803.7+/-3.3, 834.3+/-3.1 and 735.2+/-3.0 kJ mol(-1)) mean palladium-sulphur bond-dissociation enthalpies were calculated.

  DOI：

  10.1023/a:1013912207743

文献信息

• Rangel, Jose Hilton G.; Francisco Oliveira, Severino; Espinola, Jose Geraldo P., Thermochimica Acta, 1999, vol. 328, # 1-2, p. 187 - 194
  作者：Rangel, Jose Hilton G.、Francisco Oliveira, Severino、Espinola, Jose Geraldo P.、Gouveia Souza, Antonio

  DOI：——

  日期：——
• ——
  作者：J. R. Botelho、A. G. Souza、L. M. Nunes、A. P. Chagas、I. M. Garcia dos Santos、M. M. da Conceição、P. O. Dunstan

  DOI：10.1023/a:1013912207743

  日期：——

  The standard molar enthalpies of formation of crystalline dialkyldithiocarbamates chelates, [Pd(S2CNR2)(2)], with R=C2H5, n-C3H7, n-C4H9 and i-C4H9, were determined through reaction-solution calorimetry in acetone, at 298.15 K. From the standard molar enthalpies of formation of the gaseous chelates, the homolytic (172.4+/-3.8, 182.5+/-3.2, 150.9+/-3.1 and 162.6+/-3.1 kJ mol(-1)) and heterolytic (745.0+/-3.8, 803.7+/-3.3, 834.3+/-3.1 and 735.2+/-3.0 kJ mol(-1)) mean palladium-sulphur bond-dissociation enthalpies were calculated.