Bicyclo[4.2.0]oct-1(6)-en-3-yl-trichloro-silane | 134751-14-7

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: Bicyclo[4.2.0]oct-1(6)-en-3-yl-trichloro-silane
• CAS: 134751-14-7
• 化学式: C₈H₁₁Cl₃Si
• 分子量: 241.62
• InChiKey: ULMNHODYVVOZSJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.29
• 重原子数：
  12.0
• 可旋转键数：
  1.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  Bicyclo[4.2.0]oct-1(6)-en-3-yl-trichloro-silane 、 alkaline earth salt of/the/ methylsulfuric acid 以 乙醚 为溶剂， 以85%的产率得到Bicyclo[4.2.0]oct-1(6)-en-3-yl-trimethyl-silane
  参考文献：
  名称：

  Preparation of silyl derivatives of unsaturated carbocyclic compounds by the Diels-Alder reaction of 1,2-dimethylenecyclobutane and vinylsilanes

  摘要：

  The Diels-Alder reactions of 1,2-dimethylenecyclobutane with vinyltrichlorosilane and vinylmethyldichlorosilane give the corresponding trichlorosilyl and methyldichlorosilyl derivatives of cyclobutene. Methylation of these derivatives gave 4-trimethylsilylbicyclo[4.2.0]oct-1-ene, which underwent thermal isomerization to 4-trimethylsilyl-1,2-dimethylcyclohexane.

  DOI：

  10.1007/bf00958585
• 作为产物：
  描述：

  乙烯基三氯硅烷 、 1,2-二亚甲基环丁烷 以44%的产率得到Bicyclo[4.2.0]oct-1(6)-en-3-yl-trichloro-silane
  参考文献：
  名称：

  Preparation of silyl derivatives of unsaturated carbocyclic compounds by the Diels-Alder reaction of 1,2-dimethylenecyclobutane and vinylsilanes

  摘要：

  The Diels-Alder reactions of 1,2-dimethylenecyclobutane with vinyltrichlorosilane and vinylmethyldichlorosilane give the corresponding trichlorosilyl and methyldichlorosilyl derivatives of cyclobutene. Methylation of these derivatives gave 4-trimethylsilylbicyclo[4.2.0]oct-1-ene, which underwent thermal isomerization to 4-trimethylsilyl-1,2-dimethylcyclohexane.

  DOI：

  10.1007/bf00958585

文献信息

• Preparation of silyl derivatives of unsaturated carbocyclic compounds by the Diels-Alder reaction of 1,2-dimethylenecyclobutane and vinylsilanes
  作者：N. V. Ushakov、G. V. Bakulina、A. V. Patrikeev、E. B. Portnykh、V. D. Oppengeim、E. Sh. Finkel'shtein

  DOI：10.1007/bf00958585

  日期：1991.4

  The Diels-Alder reactions of 1,2-dimethylenecyclobutane with vinyltrichlorosilane and vinylmethyldichlorosilane give the corresponding trichlorosilyl and methyldichlorosilyl derivatives of cyclobutene. Methylation of these derivatives gave 4-trimethylsilylbicyclo[4.2.0]oct-1-ene, which underwent thermal isomerization to 4-trimethylsilyl-1,2-dimethylcyclohexane.