Tributyl(methoxymethyl)plumbane | 147024-41-7

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机过渡后金属化合物
• 英文名称: Tributyl(methoxymethyl)plumbane
• CAS: 147024-41-7
• 化学式: C₁₄H₃₂OPb
• 分子量: 423.607
• InChiKey: KWUBAOYYORSENU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.02
• 重原子数：
  16
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  Hexabutyl-diblei 、 氯甲基甲基醚 在 正丁基锂 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 以92%的产率得到Tributyl(methoxymethyl)plumbane
  参考文献：
  名称：

  Synthesis of α-alkoxyalkyltributyllead compounds via the reaction of tributylplumbyllithium with α-chloroethers, and the conjugate addition of tributylplumbyllithium to enones

  摘要：

  Alpha-alkoxyalkyltributylleads 1 were prepared from the reaction of tributylplumbyllithium with alpha-chloroethers 2. This procedure is more convenient than the conventional method which involves transmetallation from the corresponding alpha-alkoxyalkyltrialkyltin. Tributylplumbyllithium was also used for the synthesis of beta-oxo-organo-lead 4.

  DOI：

  10.1016/0022-328x(93)80023-5

文献信息

• Synthesis of α-alkoxyalkyltributyllead compounds via the reaction of tributylplumbyllithium with α-chloroethers, and the conjugate addition of tributylplumbyllithium to enones
  作者：Ichiro Suzuki、Toshiaki Furuta、Yoshinori Yamamoto

  DOI：10.1016/0022-328x(93)80023-5

  日期：1993.1

  Alpha-alkoxyalkyltributylleads 1 were prepared from the reaction of tributylplumbyllithium with alpha-chloroethers 2. This procedure is more convenient than the conventional method which involves transmetallation from the corresponding alpha-alkoxyalkyltrialkyltin. Tributylplumbyllithium was also used for the synthesis of beta-oxo-organo-lead 4.