3-丙烯酰胺丙基三甲氧基硅烷 | 57577-96-5

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 中文名称: 3-丙烯酰胺丙基三甲氧基硅烷
• 英文名称: 3-acrylamidopropyltrimethoxysilane
• 英文别名: N-(3-(trimethoxysilyl)propyl)acrylamide；N-(3-trimethoxysilylpropyl)prop-2-enamide
• CAS: 57577-96-5
• 化学式: C₉H₁₉NO₄Si
• 分子量: 233.34
• InChiKey: XGHNWFFWGDCAHZ-UHFFFAOYSA-N

物化性质

• 沸点：
  303.8±34.0 °C(Predicted)
• 密度：
  1.062

计算性质

• 辛醇/水分配系数(LogP)：
  0.56
• 重原子数：
  15
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  56.8
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  三聚氯氰 、 3-丙烯酰胺丙基三甲氧基硅烷 、 9,10-二氢-9-氧杂-10-磷杂菲-10-氧化物 在 sodium hydroxide 作用下， 以 二甲基亚砜 为溶剂， 反应 42.0h， 生成
  参考文献：
  名称：

  CN115073522

  摘要：

  公开号：
• 作为产物：
  描述：

  硅烷偶联剂 KH-540 、 丙烯酰氯 在 三乙胺 作用下， 以 四氢呋喃 为溶剂， 反应 3.0h， 生成 3-丙烯酰胺丙基三甲氧基硅烷
  参考文献：
  名称：

  Photocurable Amphiphilic Perfluoropolyether/Poly(ethylene glycol) Networks for Fouling-Release Coatings

  摘要：

  We demonstrate a facile way of cross-linking hydrophobic perfluoropolyethers, PFPEs, with a series of hydrophilic poly(ethylene glycol)s, PEGs, to prepare a range of amphiphilic networks for use as fouling-release coatings. The PFPE matrix of the networks endows the coating with a low surface energy while the PEG is added to weaken fouling adhesion. It is therefore envisioned that the coating surfaces of these optically transparent and mechanically robust films will display hydrophobicity leading to nonfouling and fouling release characteristics. Two kinds of functionalized PEG oligomers have been cross-linked with reactive, dimethacryloxy-functionalized PEPE oligomers to form a range of amphiphilic networks: (i) a monomethacryloxy-functionalized PEG macromonomer (454 g/mol) (PEG454-MA) which was used to yield blends with flexible PEG chains on the surface as well as in bulk and (ii) a dimethacryloxy-functionalized PEG (550 g/mol) (PEG550-DMA) which results in PEG chains that are relatively more restricted in the network blends and serve as an added difunctional cross-linker for the network along with the dimethacryloxy-functionalized PFPE. The PFPE/PEG cross-linked networks coated on a substrate show very low swelling characteristics in water when PEG454-MA comprises not more than 10 wt % of the overall composition or when PEG550-DMA is used and does not comprise more than 30 wt % of the overall composition. The PFPE/PEG454 MA coatings having PEG chains with one untethered chain end were found to display relatively high spore and barnacle release performance in comparison to PFPE/PEG550-DMA coatings which have the PEG chains in a more restricted network topology.

  DOI：

  10.1021/ma102271t

文献信息

• Process for the synthesis of acylamino organosilicon compounds
  申请人：Dow Corning Corporation

  公开号：US04861906A1

  公开（公告）日：1989-08-29

  Organosilicon compounds containing at least one acylamino-substituted hydrocarbon radical are prepared by reacting an organosilicon compound containing at least one amino-substituted hydrocarbon radical with an acyl halide in a nonaqueous solvent and in the presence of a metal alkoxide in a nonaqueous cosolvent.

  含有至少一个酰胺取代的碳氢基团的有机硅化合物是通过在非水溶剂和非水共溶剂中，在金属烷氧化物的存在下，将至少含有一个氨基取代的碳氢基团的有机硅化合物与酰卤反应而制备的。
• Photofunctional Eu3+/Tb3+ hybrid material with inorganic silica covalently linking polymer chain through their double functionalization
  作者：Bing Yan、Qian Kai、Xiao-Long Wang

  DOI：10.1016/j.ica.2011.06.036

  日期：2011.10

  In the context, 2-thiosalicylic acid (TSA) is modified with two crosslinking reagents (3-chloropropyltrimethoxysilane (CTPMS), 3-(triethoxysilyl)-propyl isocyanate (TESPIC)) to achieve two kinds of sulfide bridges (abbreviated as TSA-CSi and TSA-TSi, respectively). And two organic polymers (poly acrylamide (PAM) and poly ethylene glycol (PEG)) are also functionalized with TESPIC to form their polymeric silane derivatives PAMSi and PEGSi. Then series of multi-component Eu3+/Tb3+ hybrid material have been assembled with inorganic silica covalently linking organic polymer through the sulfide bridges after co-hydrolysis and co-polycondensation with the above inorganic or organic alkoxyl compounds (TSA-CSi(TSi), PAMSi(PEGSi)) and tetraethoxysilane (TEOS). These hybrid material are characterized in details to compare with the binary hybrid material without organic polymer unit, whose results reveal that the photoluminescence properties of the hybrid system are improved with the introduction of the polymer unit. (C) 2011 Elsevier B. V. All rights reserved.
• VARAPRATH, SUDARSANAN;VARAPRATH, PADMAKUMARI J.
  作者：VARAPRATH, SUDARSANAN、VARAPRATH, PADMAKUMARI J.

  DOI：——

  日期：——
• Photocurable Amphiphilic Perfluoropolyether/Poly(ethylene glycol) Networks for Fouling-Release Coatings
  作者：Yapei Wang、Douglas E. Betts、John A. Finlay、Lenora Brewer、Maureen E. Callow、James A. Callow、Dean E. Wendt、Joseph M. DeSimone

  DOI：10.1021/ma102271t

  日期：2011.2.22

  We demonstrate a facile way of cross-linking hydrophobic perfluoropolyethers, PFPEs, with a series of hydrophilic poly(ethylene glycol)s, PEGs, to prepare a range of amphiphilic networks for use as fouling-release coatings. The PFPE matrix of the networks endows the coating with a low surface energy while the PEG is added to weaken fouling adhesion. It is therefore envisioned that the coating surfaces of these optically transparent and mechanically robust films will display hydrophobicity leading to nonfouling and fouling release characteristics. Two kinds of functionalized PEG oligomers have been cross-linked with reactive, dimethacryloxy-functionalized PEPE oligomers to form a range of amphiphilic networks: (i) a monomethacryloxy-functionalized PEG macromonomer (454 g/mol) (PEG454-MA) which was used to yield blends with flexible PEG chains on the surface as well as in bulk and (ii) a dimethacryloxy-functionalized PEG (550 g/mol) (PEG550-DMA) which results in PEG chains that are relatively more restricted in the network blends and serve as an added difunctional cross-linker for the network along with the dimethacryloxy-functionalized PFPE. The PFPE/PEG cross-linked networks coated on a substrate show very low swelling characteristics in water when PEG454-MA comprises not more than 10 wt % of the overall composition or when PEG550-DMA is used and does not comprise more than 30 wt % of the overall composition. The PFPE/PEG454 MA coatings having PEG chains with one untethered chain end were found to display relatively high spore and barnacle release performance in comparison to PFPE/PEG550-DMA coatings which have the PEG chains in a more restricted network topology.
• CN115073522
  申请人：——

  公开号：——

  公开（公告）日：——