Germylacetylen | 7282-87-3

• 分子结构分类: 有机化合物 - 乙炔化物 - 碳化物
• 英文名称: Germylacetylen
• 英文别名: Germylacetylene；ethynylgermane
• CAS: 7282-87-3
• 化学式: C₂H₄Ge
• 分子量: 100.644
• InChiKey: AOZJZWCWZVENEF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.06
• 重原子数：
  3
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  乙炔基三氯锗烷 、 lithium aluminium tetrahydride 以 further solvent(s) 为溶剂， 以47%的产率得到Germylacetylen
  参考文献：
  名称：

  Photoelectron spectra of vinyl- and 1-alkynylgermanes and stannanes

  摘要：

  Primary vinylic and acetylenic germanes and stannanes, synthesized by a chemoselective reduction of the corresponding trichloro derivatives, were investigated by ab initio quantum chemical methods and photoelectron spectroscopy. In particular, the PE spectra display very well-resolved bands which show the increasing destabilizing effect of 14 group heteroatom cl-substitution of double or triple carbon-carbon bonds. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)00718-9

文献信息

• Photoelectron spectra of vinyl- and 1-alkynylgermanes and stannanes
  作者：Anna Chrostowska、Véronique Métail、Geneviève Pfister-Guillouzo、Jean-Claude Guillemin

  DOI：10.1016/s0022-328x(98)00718-9

  日期：1998.11

  Primary vinylic and acetylenic germanes and stannanes, synthesized by a chemoselective reduction of the corresponding trichloro derivatives, were investigated by ab initio quantum chemical methods and photoelectron spectroscopy. In particular, the PE spectra display very well-resolved bands which show the increasing destabilizing effect of 14 group heteroatom cl-substitution of double or triple carbon-carbon bonds. (C) 1998 Elsevier Science S.A. All rights reserved.