Nickel;tantalum | 12035-73-3

• 分子结构分类: 无机化合物 - 均相金属化合物 - 均相过渡金属化合物
• 英文名称: Nickel;tantalum
• 英文别名: nickel;tantalum
• CAS: 12035-73-3
• 化学式: Ni₃Ta
• 分子量: 357.018
• InChiKey: UPSVXOVJGGIIEJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.01
• 重原子数：
  4
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  反应 24.0h， 生成 Nickel;tantalum
  参考文献：
  名称：

  Separating the strengthening phase in nickel–cobalt alloys doped with tantalum

  摘要：

  The hardness values of monophasic (fcc solid solution) and biphasic (fcc solid solution and separated phase) nickel-cobalt alloys doped with tantalum are determined using the Vickers method. Based on the resulting data, a composition-structure-hardness diagram is devised for the Co-Ni-Ta system.

  DOI：

  10.1134/s0036024417020273

文献信息

• Intermetallic Ni₂Ta Electrocatalyst for the Oxygen Evolution Reaction in Highly Acidic Electrolytes
  作者：Jared S. Mondschein、Kuldeep Kumar、Cameron F. Holder、Kriti Seth、Hojong Kim、Raymond E. Schaak

  DOI：10.1021/acs.inorgchem.8b00503

  日期：2018.5.21

  oxygen evolution reaction (OER) in highly acidic electrolytes is a critical bottleneck in the development of many water-splitting technologies. Bulk-scale solid-state compounds can be readily produced using high-temperature reactions and therefore used to expand the scope of earth-abundant OER catalysts capable of operating under strongly acidic conditions. Here, we show that high temperature arc melting

  能够催化高酸性电解质中的氧释放反应（OER）的材料的鉴定是许多水分解技术发展中的关键瓶颈。大规模固态化合物可以使用高温反应轻松生产，因此可用于扩展能够在强酸性条件下运行的富含地球的OER催化剂的范围。在这里，我们表明，高温电弧熔化和粉末冶金反应可用于合成由金属间化合物Ni 2 Ta组成的电极，该电极可在0.50 MH 2 SO 4中催化OER 。电弧熔化的Ni 2 Ta电极以10 mA / cm 2的电流密度释放出氧气腐蚀时间> 66 h，腐蚀速率比纯Ni腐蚀速率低2个数量级。多晶Ni 2 Ta粒料产生10 mA / cm 2的电流密度所需的过电势为570 mV。该策略可以推广到包括其他第一行过渡金属，包括金属间Fe 2 Ta和Co 2 Ta体系。
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Ni: MVol.B1, 58, page 166 - 168
  作者：

  DOI：——

  日期：——
• Influence of anisotropy, the latent heat and the thermal history of alloy on martensitic transformation strain in Ni3Ta single crystal
  作者：A. Rudajevová、J. Pospíšil

  DOI：10.1016/j.jallcom.2011.02.095

  日期：2011.5

  Transformation characteristics in the single crystal of Ni3Ta shape memory alloy were studied by the dilatation measurement in the temperature range of room temperature up to 500 degrees C. The transformation strains were positive in the direction of the b-axes and the c-axes and negative in the direction of a-axes. The martensitic phase transformation takes place without volume change of the sample. Thermal diffusivity of the single crystal measured in two directions b-axes and a-axes was higher than that for polycrystalline material.The latent heat of the martensitic phase transformation influences the temperature distribution inside sample. Absorption (releasing) of the latent heat during heating (cooling) leads to cooling (heating) of the sample in place where the phase transformation takes place. This decrease (increase) of the temperature in the interface between both phases leads to stopping of the phase transformation. This effect is visible on the temperature dependence of the dilatation characteristics. The martensitic phase transformation in Ni3Ta single crystal took place with hysteresis of 30 degrees C. This hysteresis changes depending on the thermal history of the sample. Hysteretic behaviour of the Ni3Ta single crystal was analyzed and compared with behaviour of Ni53.6Mn27.1Ga19.3 alloy where no hysteresis was found. (C) 2011 Elsevier B.V. All rights reserved.
• Kornilov, I. I.; Pylaeva, E. N., Doklady Akademii Nauk SSSR, 1954, vol. 97, p. 455 - 457
  作者：Kornilov, I. I.、Pylaeva, E. N.

  DOI：——

  日期：——
• Chance, M. H. La; Jaffee, R. I., Transactions of the American Society for Metals, 1955, vol. 48, p. 595 - 626
  作者：Chance, M. H. La、Jaffee, R. I.

  DOI：——

  日期：——