Molybdenum--zirconium (2/1) | 12033-35-1

• 分子结构分类: 无机化合物 - 均相金属化合物 - 均相过渡金属化合物
• 英文名称: Molybdenum--zirconium (2/1)
• 英文别名: molybdenum;zirconium
• CAS: 12033-35-1
• 化学式: Mo₂Zr
• 分子量: 283.104
• InChiKey: KVMWOOXRTBUMIS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.01
• 重原子数：
  3
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  氢气 、 Molybdenum--zirconium (2/1) 以 neat (no solvent) 为溶剂， 生成
  参考文献：
  名称：

  Hydrogen motion inC15-typeZrMo2Hx:Quasielastic neutron scattering and nuclear-magnetic-resonance studies

  摘要：

  DOI：

  10.1103/physrevb.60.7238
• 作为产物：
  描述：

  氯化锆(IV) 、 钼 在 氢气 作用下， 生成 Molybdenum--zirconium (2/1)
  参考文献：
  名称：

  Prokoshkin, D. A.; Arzamasov, B. N., Issledovaniya po Zharoprochnym Splavam, 1962, vol. 9, p. 177 - 183

  摘要：

  DOI：

文献信息

• Khan, Ashraf Z., Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 1987, vol. 26, # 8, p. 662 - 666
  作者：Khan, Ashraf Z.

  DOI：——

  日期：——
• ——
  作者：S. P. Shilkin

  DOI：10.1023/a:1020898906508

  日期：——

  Reaction of hydride phases of zirconium intermetallic compounds with molecular nitrogen was studied at 293 and 973 K and nitrogen pressure of 10 MPa. At 293 K, hydride-nitride phases crystallizing in the structural types of the initial hydride phases are formed in all cases, whereas at 973 K finely dispersed heterophase mixtures of zirconium, molybdenum, and vanadium nitrides with 3d transition metals or mixtures of zirconium nitride with vanadium, molybdenum, chromium, and manganese nitrides are formed.
• Afanas'ev, P. V.; Manovyan, K. A.; Lunin, V. V., Doklady Physical Chemistry, 1991, vol. 318, p. 461 - 464
  作者：Afanas'ev, P. V.、Manovyan, K. A.、Lunin, V. V.

  DOI：——

  日期：——
• The effects of pretreatments on the catalyticactivities of hydrogen storage intermetallics
  作者：Lu-Zhuang Wang、Yong-Quan Lei、Jing Wu、Qi-Dong Wang、Feng-Qi Ma、Bing-Ling Liu

  DOI：10.1016/s0022-5088(06)80016-0

  日期：1991.1

  The effects of different pretreatments, including pulverizing, oxidizing, immersing in basic solution and pickling in acid solutions, on the catalytic activities of hydrogen storage intermetallics used for the hydrogenation of cyclohexene have been studied. Reaction experiments were carried out in a pulse microreactor with gas chromatography equipment on line.Experimental results show that all four pretreatment methods have beneficial effects on the catalytic hydrogenation activities of the hydrogen storage intermatallics, with a maximum increase in reaction rate up to 2 orders of magnitude. On studying the crystal structures, surface compositions and the specific surface areas of the catalysts, the present authors believe that on pretreatment the increase in activity may be ascribed to an increase in the specific surface area and the enrichment of active metals on the surfaces.
• Metal-metalloid exchange in the Zr1−xMxMo2 (M ≡; Ge, Si, Al) system
  作者：Ž. Blažina、R. Trojko、Z. Ban

  DOI：10.1016/0022-5088(84)90012-2

  日期：1984.2