1,3,5-Tris[2-(6-oxobenzo[c][2,1]benzoxaphosphinin-6-yl)ethyl]-1,3,5-triazinane-2,4,6-trione | 884320-65-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: 1,3,5-Tris[2-(6-oxobenzo[c][2,1]benzoxaphosphinin-6-yl)ethyl]-1,3,5-triazinane-2,4,6-trione
• CAS: 884320-65-4
• 化学式: C₄₅H₃₆N₃O₉P₃
• 分子量: 855.717
• InChiKey: CYHKNBGPSPTXIT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.2
• 重原子数：
  60
• 可旋转键数：
  9
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.13
• 拓扑面积：
  140
• 氢给体数：
  0
• 氢受体数：
  9

反应信息

• 作为反应物：
  描述：

  1,3,5-Tris[2-(6-oxobenzo[c][2,1]benzoxaphosphinin-6-yl)ethyl]-1,3,5-triazinane-2,4,6-trione 在 硝酸 、 乙酸酐 作用下， 反应 5.67h， 生成 、 、 、
  参考文献：
  名称：

  WO2006/84489

  摘要：

  公开号：
• 作为产物：
  描述：

  1,3,5-三(2-羟乙基)氰尿酸 在 对甲苯磺酸甲酯 作用下， 135.0~175.0 ℃ 、999.92 Pa 条件下， 反应 39.0h， 生成 1,3,5-Tris[2-(6-oxobenzo[c][2,1]benzoxaphosphinin-6-yl)ethyl]-1,3,5-triazinane-2,4,6-trione
  参考文献：
  名称：

  A Novel and Effective Synthetic Approach to 9,10-Dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO) Derivatives

  摘要：

  DOPO and its derivatives generally exhibit an outstanding performance as flame retardants in various polymers. Starting from trivalent 10-alkoxy-10H-9-oxa-10-phosphaphenanthrenes, a broad range of DOPO derivatives was synthesized via transesterification with aliphatic alcohols and subsequent Michaelis-Arbuzou rearrangement using catalytic amounts of p-toluenesulfonic acid methylester. Due to the considerable differences in the nature of the alcohols employed, several procedures for processing them are presented.

  DOI：

  10.1080/10426500701407417

文献信息

• METHOD FOR THE PRODUCTION OF BRIDGED DIBENZ[c,e] [1,2]-OXAPHOSPHORIN-6-OXIDES
  申请人：Döring Manfred

  公开号：US20100168423A1

  公开（公告）日：2010-07-01

  The invention relates to an improved method for the synthesis of monomeric and polymeric nitrogen-bridged derivatives of dibenz[c,e][1,2]-oxaphosphorin-6-oxides. These substances can be used as flameproofing agents for polyesters, polyamides, polycarbonates, epoxy resins, inter alia polymers.

  本发明涉及一种改进的方法，用于合成二苯并[c,e][1,2]-氧磷杂环戊烷-6-氧化物的单体和聚合物氮桥衍生物。这些物质可以用作聚酯，聚酰胺，聚碳酸酯，环氧树脂等聚合物的阻燃剂。
• MELAMINE PHENYLPHOSPHONATE FLAME RETARDANT COMPOSITIONS
  申请人：Fuchs Sabine

  公开号：US20110266507A1

  公开（公告）日：2011-11-03

  The present invention relates to flame retardant polymer compositions which comprise melamine phenylphosphonates and mixtures with dihydro-oxa-phosphaphenanthrene derivatives. The compositions are especially useful for the manufacture of flame retardant compounds based on polyfunctional epoxides or polycondensates like polyesters, polyamides and polycarbonates.

  本发明涉及阻燃聚合物组合物，其包括三聚氰胺苯基膦酸盐和与二氢氧磷菲衍生物混合物。该组合物特别适用于基于多功能环氧化合物或聚酯，聚酰胺和聚碳酸酯的阻燃化合物的制造。
• MELAMINE PHENYLPHOSPHINATE FLAME RETARDANT COMPOSITIONS
  申请人：Fuchs Sabine

  公开号：US20110288206A1

  公开（公告）日：2011-11-24

  The present invention relates to flame retardant polymer compositions which comprise melamine phenylphosphinates and mixtures with dihydro-oxa-phosphaphenanthrene derivatives. The compositions are especially useful for the manufacture of flame retardant compounds based on polyfunctional epoxides or polycondensates like polyesters, polyamides and polycarbonates.

  本发明涉及一种阻燃聚合物组合物，其包括三聚氰胺苯基膦酸盐和二氢氧化磷酞类衍生物的混合物。该组合物特别适用于制造基于多官能团环氧树脂或聚酯、聚酰胺和聚碳酸酯的阻燃化合物。
• GLOW-WIRE RESISTANT POLYAMIDES
  申请人：Roth Michael

  公开号：US20120157589A1

  公开（公告）日：2012-06-21

  Thermoplastic molding compositions comprising A) from 29 to 97.5% by weight of a thermoplastic polyamide, B) from 1 to 20% by weight of melamine cyanurate, C) from 0.5 to 10% by weight of an organic phosphorus compound based on 9,10-dihydro-9-oxa-10-phosphaphenanthrene oxide (DOPO) as parent structure, D) from 1 to 50% by weight of a fibrous filler, the aspect ratio (L/D) of which is from 4 to 25, and the arithmetic average fiber length of which is from 40 to 250 μm, and E) from 0 to 50% by weight of further additives, where the total of the percentages by weight of components A) to E) is 100%.

  热塑性聚合物成型组合物，包括： A) 29-97.5重量％的热塑性聚酰胺 B) 1-20重量％的三聚氰酸蜜胺 C) 0.5-10重量％的有机磷化合物，基于9,10-二氢-9-氧杂-10-膦杂菲氧化物（DOPO）作为母体结构 D) 1-50重量％的纤维填料，其长宽比（L/D）为4-25，算术平均纤维长度为40-250μm E) 0-50重量％的进一步添加剂 其中，组分A）到E）的重量百分比总和为100％。
• DOPO FLAME RETARDANT COMPOSITIONS
  申请人：Roth Michael

  公开号：US20100234495A1

  公开（公告）日：2010-09-16

  The present invention relates to flame retardant polymer compositions which comprise mixtures of phosphinic acid salts and dihydro-oxa-phospho-phenantrene derivatives. The compositions are especially useful for the manufacture of flame retardant compounds based on polycondensates like polyesters, polyamides and polycarbonates.