[Nd(DMF)₄(H2O)₃(μ-CN)Fe(CN)₅]*H₂O | 557077-64-2

• 分子结构分类: 有机化合物 - 有机盐
• 英文名称: [Nd(DMF)₄(H2O)₃(μ-CN)Fe(CN)₅]*H₂O
• 英文别名: [tetrakis(N,N'-dimethylformamide)triaquaneodymium(III)-μ-cyano-pentacyanoiron(III)] * water；Nd(H2O)3(N,N-dimethylformamide)4(μ-CN)Fe(CN)5*H2O；Nd(N,N-dimethylformamide)4(H2O)3(μ-CN)Fe(CN)5*H2O；[Nd(DMF)4(H2O)3(μ-CN)Fe(CN)5]*H2O；Nd(DMF)4(H2O)3(μ-CN)Fe(CN)5*H2O；N,N-dimethylformamide;iron(3+);neodymium(3+);hexacyanide;tetrahydrate
• CAS: 557077-64-2；623566-62-1
• 化学式: C₁₈H₃₄FeN₁₀NdO₇*H₂O
• 分子量: 720.633
• InChiKey: OZPDZLRSNQWFHX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -3.91
• 重原子数：
  38
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.44
• 拓扑面积：
  228
• 氢给体数：
  4
• 氢受体数：
  20

反应信息

• 作为产物：
  描述：

  三氯化钕 、 N,N-二甲基甲酰胺 、 potassium hexacyanoferrate(III) 以 水 、 N,N-二甲基甲酰胺 为溶剂， 生成 [Nd(DMF)₄(H2O)₃(μ-CN)Fe(CN)₅]*H₂O
  参考文献：
  名称：

  X射线衍射分析氰基桥联异双金属配合物的光磁性能

  摘要：

  已经在[N​​d（DMF）4（H 2 O）3（μ-CN）Fe（CN）5 ]·H 2 O（DMF =二甲基甲酰胺）1上进行了单晶同步加速器X射线衍射测量；[Y（DMF）4（H 2 O）3（μ-CN）Fe（CN）5 ]·H 2 O，2；[Ce（DMF）4（H 2 O）3（μ-CN）Fe（CN）5 ]·H 2 O，3；[Sm（DMF）4（H 2 O）3（μ-CN）Fe（CN）5 ]·H 2O，4；[Tb（DMF）4（H 2 O）3（μ-CN）Fe（CN）5 ]·H 2 O，5；[Yb（DMF）4（H 2 O）3（μ-CN）Fe（CN）5 ]·H 2 O，6；和[Nd（DMF）4（H 2 O）3（μ-CN）Co（CN）5 ]·H 2 O，7在15（2）K下有和没有晶体的紫外线照射。观察到所有含铁配合物的晶胞参数均发生了显着变化，而化合物7对紫外线没有反应。这些结果与先前的结果一致，并且进一步通过化

  DOI：

  10.1021/ic2015258

文献信息

• High pressure induced charge transfer in 3d–4f bimetallic photomagnetic materials
  作者：Lai-Chin Wu、Morten Bormann Nielsen、Martin Bremholm、Solveig Røgild Madsen、Jacob Overgaard、Matt Newville、Yu-Sheng Chen、Bo Brummerstedt Iversen

  DOI：10.1039/c5cc00603a

  日期：——

  A non-hydrostatic pressure induces ligand to metal charge transfer on the iron site of a 3d–4f photomagnetic material.

  一个非静水压力在3d-4f光磁性材料的铁位点上引发了配体向金属的电荷转移。
• Photoinduced Magnetization of the Cyano-Bridged 3d−4f Heterobimetallic Assembly Nd(DMF)₄(H₂O)₃(μ-CN)Fe(CN)₅·H₂O (DMF = <i>N</i>,<i>N</i>-Dimethylformamide)
  作者：Guangming Li、Takashiro Akitsu、Osamu Sato、Yasuaki Einaga

  DOI：10.1021/ja037183k

  日期：2003.10.1

  Photoinduced magnetization of the cyano-bridged 3d-4f heterobimetallic assembly Nd(DMF)4(H2O)3(mu-CN)Fe(CN)5.H2O (1) (DMF = N,N-dimethylformamide) is described in this paper. The chiMT values are enhanced by about 45% after UV light illumination in the temperature range of 5-50 K. We propose that UV light illumination induces a structural distortion in 1. This small structural change is propagated by molecular interactions in the inorganic network. Furthermore, the cooperativity resulting from the molecular interaction functions to increase the activation energy of the relaxation processes, which makes observation of the photoexcited state possible. The flexible network structure through the hydrogen bonds in 1 plays an essential role for the photoinduced phenomenon. This finding may open up a new domain for developing the molecule-based magnetic materials.
• Svendsen, Helle; Overgaard, Jacob; Chevallier, Marie, Angewandte Chemie - International Edition, 2009, vol. 48, p. 2780 - 2783
  作者：Svendsen, Helle、Overgaard, Jacob、Chevallier, Marie、Collet, Eric、Iversen, Bo B.

  DOI：——

  日期：——
• Synthesis and Characterization of Heterodinuclear Ln³⁺−Fe³⁺ and Ln³⁺−Co³⁺ Complexes, Bridged by Cyanide Ligand (Ln³⁺ = Lanthanide Ions). Nature of the Magnetic Interaction in the Ln³⁺−Fe³⁺ Complexes
  作者：Albert Figuerola、Carmen Diaz、Joan Ribas、Vassilis Tangoulis、Jaume Granell、Francesc Lloret、José Mahía、Miguel Maestro

  DOI：10.1021/ic025669g

  日期：2003.1.1

  The reaction of Ln(NO3)(3).aq with K-3[Fe(CN)(6)] Or K-3[Co(CN)(6)] in N,N'-dimethyltormamide (DMF) led to 25 heterodinuclear [Ln(DMF)(4)(H2O)(3)(mu-CN)Fe(CN)(5)]-nH(2)O and [Ln(DMF)(4)(H2O)(3)(mu-CN)Co(CN)(5)].nH(2)O complexes (with Ln = all the lanthanide(III) ions, except promethium and lutetium). Five complexes (Pr3+-Fe3+), (Tm3+-Fe3+), (Ce3+-Co3+), (Sm3+-Co3+), and (Yb3+-Co3+) have been structurally characterized; they crystallize in the equivalent monoclinic space groups P2(1)/c or P2(1)/n. Structural studies of these two families show that they are isomorphous. This relationship in conjunction with the diamagnetism of the Co3+ allows an approximation to the nature of coupling between the iron(III) and the lanthanide(III) ions in the [Ln(DMF)(4)(H2O)(3)(mu-CN)Fe(CN)(5)]-nH(2)O complexes. The Ln(3+)-Fe3+ interaction is antiferromagnetic for Ln = Ce, Nd, Gd, and Dy and ferromagnetic for Ln = Tb, Ho, and Tm. For Ln = Pr, Eu, Er, Sm, and Yb, there is no sign of any significant interaction. The isotropic nature of Gd3+ helps to evaluate the value of the exchange interaction.