triphenylstannyl 4-methylpiperazine-1-carbodithioate | 180138-90-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪烷类
• 英文名称: triphenylstannyl 4-methylpiperazine-1-carbodithioate
• CAS: 180138-90-3
• 化学式: C₂₄H₂₆N₂S₂Sn
• 分子量: 525.326
• InChiKey: MGNUAPMRWZHRMU-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  三苯基氯化锡 、 sodium 4-methyl-1-piperazinecarbodithioate 以 苯 为溶剂， 以89%的产率得到triphenylstannyl 4-methylpiperazine-1-carbodithioate
  参考文献：
  名称：

  SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF HETEROCYCLIC DITHIOCARBAMATE COMPLEXES OF TRIORGANOTIN (IV)

  摘要：

  Heterocyclic dithiocarbamate complexes of triorganotin (IV) having general formula, CH(2)CH(2)XCH(2)NCS(2)SnR(3) (where X = >CH2, >CH-CH3, >N-CH3, >O; R = -CH3 and C6H5) have been synthesized by the reaction of triorganotin chloride with the sodium salt of the corresponding ligand in 1:1 stoichiometry. These complexes have been characterized by elemental analysis, molecular weight measurements, IR and NMR (H-1, C-13,d Sn-119) spectroscopy, suggesting that the methyl tin complexes are probably four coordinate, while the phenyl tin ones are probably five-coordinate with bidentate dithiocarbamate.

  DOI：

  10.1080/10426509608046344