[Ag(tricyanomethanide)(1,4-diazobicyclo[2.2.2]octane)] | 517864-84-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪烷类
• 英文名称: [Ag(tricyanomethanide)(1,4-diazobicyclo[2.2.2]octane)]
• CAS: 517864-84-5
• 化学式: Ag*C₄N₃*C₆H₁₂N₂
• 分子量: 310.107
• InChiKey: BIPXWSYJKBPETC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.25
• 重原子数：
  16.0
• 可旋转键数：
  0.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  77.85
• 氢给体数：
  0.0
• 氢受体数：
  5.0

反应信息

• 作为产物：
  描述：

  三乙烯二胺 、 silver(I) tricyanomethanide 以 乙腈 为溶剂， 以84%的产率得到[Ag(tricyanomethanide)(1,4-diazobicyclo[2.2.2]octane)]
  参考文献：
  名称：

  AgC(CN)₃-Based Coordination Polymers

  摘要：

  Reaction of Ag(tcm), tcm = tricyanomethanide, C(CN)(3)(-), with a range of terminal and bridging ligands results in formation of a series of new coordination polymers. Recrystallization of Ag(tcm) from acetonitrile generates Ag-(tcm)(MeCN), which is composed of corrugated (6,3) sheets displaying two-fold 2D --> 2D parallel interpenetration and is topologically identical to the parent Ag(tcm) structure. Ag(tcm)(L) species, L = 1,4-diazobicyclo-(2.2.2]-octane (dabco) or 4,4'-bipyridine (bipy), contain two interpenetrating 3D networks composed of 3-connecting (tcm) and 5-connecting (Ag) centers. The structure of Ag(tcm)(bpe), bpe = 1.2-bis(4-pyridyl)ethene, contains 1D ladderlike polymers connected by weak Ag-tcm interactions into two interpenetrating 3D nets. Ag(tcm)(Mepyz)(32), Mepyz = methylpyrazine, also contains 1D ladders, while Ag(tcm)(Me(4)pyz)(1 2), Me(4)pyz = tetramethylpyrazine, contains 2D sheets composed of Ag(tcm) 1D "tubes" linked by bridging Me(4)pyz ligands. Ag(tcm)(hmt), hmt = hexamethylenetetramine, has a 3D network structure in which the hmt ligands are 3-connecting, the tcm anions are 2-connecting, and the! silver atoms are 5-connecting. The topology is the same as displayed by Ag(tcm)(L), L = dabco or bipy.

  DOI：

  10.1021/ic026189s