trans-[FeH(hydrazine-(15)N)(dmpe)2]Cl | 1309934-78-8

• 分子结构分类: 有机化合物 - 有机盐
• 英文名称: trans-[FeH(hydrazine-(15)N)(dmpe)2]Cl
• 英文别名: trans-[FeH(hydrazine-(15)N)(1,2-bis(dimethylphosphino)ethane)2]Cl
• CAS: 1309934-78-8；1309772-88-0
• 化学式: C₁₂H₃₇FeN₂P₄*Cl
• 分子量: 426.621
• InChiKey: HWGZUKCXZQJULY-HIUQERSQSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  trans-[FeH(hydrazine-(15)N)(dmpe)2]Cl 在 potassium tert-butoxide 作用下， 以 四氢呋喃 为溶剂， 生成 trans-[FeH((15)N2H3)(dmpe)] 、 cis-[FeH((15)N2H3)(dmpe)]
  参考文献：
  名称：

  Synthesis and Characterization of Iron(II) and Ruthenium(II) Hydrido Hydrazine Complexes

  摘要：

  Treatment of trans-[MHCl(dmpe)(2)] (M = Fe, Ru) with hydrazine afforded the hydrido hydrazine complexes cis- and trans-[MH(N2H4)(dmpe)(2)](+) which have been characterized by NMR spectroscopy (H-1, P-31, and N-15). Both cis and trans isomers of the Fe complex and the trans isomer of the Ru complex were characterized by X-ray crystallography. Reactions with acid and base afforded a range of N2Hx complexes, including several unstable hydrido hydrazido complexes.

  DOI：

  10.1021/ic102519f
• 作为产物：
  描述：

  trans-FeHCl(dmpe)2 、 [¹⁵N₂]-hydrazine 以 四氢呋喃 、 氘代四氢呋喃 为溶剂， 生成 trans-[FeH(hydrazine-(15)N)(dmpe)2]Cl
  参考文献：
  名称：

  Synthesis and Characterization of Iron(II) and Ruthenium(II) Hydrido Hydrazine Complexes

  摘要：

  Treatment of trans-[MHCl(dmpe)(2)] (M = Fe, Ru) with hydrazine afforded the hydrido hydrazine complexes cis- and trans-[MH(N2H4)(dmpe)(2)](+) which have been characterized by NMR spectroscopy (H-1, P-31, and N-15). Both cis and trans isomers of the Fe complex and the trans isomer of the Ru complex were characterized by X-ray crystallography. Reactions with acid and base afforded a range of N2Hx complexes, including several unstable hydrido hydrazido complexes.

  DOI：

  10.1021/ic102519f