N,N-bis(5,5,5-triphenylpentyl)aniline | 1478860-12-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 三苯基化合物
• 英文名称: N,N-bis(5,5,5-triphenylpentyl)aniline
• CAS: 1478860-12-6
• 化学式: C₅₂H₅₁N
• 分子量: 689.984
• InChiKey: BFSPPPADXDVOPE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.9
• 重原子数：
  53.0
• 可旋转键数：
  17.0
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.19
• 拓扑面积：
  3.24
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  N,N-bis(5,5,5-triphenylpentyl)aniline 在 哌啶 、 三氯氧磷 作用下， 反应 9.0h， 生成 2-(4-(bis(5,5,5-triphenylpentyl)amino)benzylidene)-5-(tert-butyl)-1H-indene-1,3(2H)-dione
  参考文献：
  名称：

  Modular approach to obtaining organic glasses from low-molecular weight dyes using 1,1,1-triphenylpentane auxiliary groups: Nonlinear optical properties

  摘要：

  A new modular synthetic approach to obtain organic glasses from low-molecular weight azobenzenes and stilbenes has been accomplished using 1,1,1-triphenylpentane crystallization preventing auxiliary groups. Six new structures show excellent solubility in non-polar solvents and thin films with good optical qualities have been obtained using a spin-coating technique. The glass transition temperatures of the new amorphous materials were in the range of 73-108 degrees C. The nonlinear optical activity in thin amorphous films was measured after a corona poling procedure. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2013.08.020
• 作为产物：
  描述：

  1,1,1-triphenylpentan-5-iodide 、 苯胺 在 potassium carbonate 作用下， 以 丙酮 为溶剂， 反应 48.0h， 以97%的产率得到N,N-bis(5,5,5-triphenylpentyl)aniline
  参考文献：
  名称：

  Modular approach to obtaining organic glasses from low-molecular weight dyes using 1,1,1-triphenylpentane auxiliary groups: Nonlinear optical properties

  摘要：

  A new modular synthetic approach to obtain organic glasses from low-molecular weight azobenzenes and stilbenes has been accomplished using 1,1,1-triphenylpentane crystallization preventing auxiliary groups. Six new structures show excellent solubility in non-polar solvents and thin films with good optical qualities have been obtained using a spin-coating technique. The glass transition temperatures of the new amorphous materials were in the range of 73-108 degrees C. The nonlinear optical activity in thin amorphous films was measured after a corona poling procedure. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2013.08.020