diethyltin(IV) bis[4-(4-methoxyphenyl)piperazine-1-carbodithioate] | 1337994-04-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪烷类
• 英文名称: diethyltin(IV) bis[4-(4-methoxyphenyl)piperazine-1-carbodithioate]
• CAS: 1337994-04-3
• 化学式: C₂₈H₄₀N₄O₂S₄Sn
• 分子量: 711.625
• InChiKey: SIIQHBFSLCUSDJ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  4-(4-methoxyphenyl)piperazinium 4-(4-methoxyphenyl)piperazine-1-carbodithioate 、 二乙基二氯化锡 以 甲醇 为溶剂， 以80%的产率得到diethyltin(IV) bis[4-(4-methoxyphenyl)piperazine-1-carbodithioate]
  参考文献：
  名称：

  Synthesis, spectroscopic properties, X-ray single crystal analysis and antimicrobial activities of organotin(IV) 4-(4-methoxyphenyl)piperazine-1-carbodithioates

  摘要：

  A series of mononuclear organotin(IV) complexes of the types, R3SnL {R = C4H9 (1), C6H11 (2), CH3 (3) and C6H5 (4)}, R2SnClL {R = C4H9 (5), C2H5 (7) and CH3 (9)} and R2SnL2 {R = C4H9 (6), C2H5 (8) and CH3 (10)}, have been synthesized, where L = 4-(4-methoxyphenyl)piperazine-1-carbodithioate. The ligand-salt and the complexes have been characterized by Raman, FT-IR and multinuclear NMR (H-1, C-13 and Sn-119) spectroscopy and elemental microanalysis (CHNS). The spectroscopic data substantiate coordination of the ligands to the organotin moieties. The structures of complexes 4 and 6 have been determined by single-crystal X-ray diffraction and illustrate the asymmetric bidentate bonding of the ligand. The packing diagrams indicate O center dot center dot center dot H and pi center dot center dot center dot H intermolecular interactions in complex 4 and intermolecular S2C center dot center dot center dot H interactions in complex 6, resulting in layer structures for both complexes. A subsequent antimicrobial study indicates that the compounds are active biologically and may well be the basis for a new class of fungicides. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.06.055