[Pt(N,N'-dimethyl-piperazine-2,3-dithione)2][Pt(CN)4] | 693219-18-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪烷类
• 英文名称: [Pt(N,N'-dimethyl-piperazine-2,3-dithione)2][Pt(CN)4]
• 英文别名: [Pt(Me2pipdt)2][Pt(CN)4]
• CAS: 693219-18-0
• 化学式: C₄N₄Pt*C₁₂H₂₀N₄PtS₄
• 分子量: 842.812
• InChiKey: WJPXSYDILAFYHK-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  bis(tetra-n-butylammonium) tetracyanoplatinate(II) 、 bis(N,N'-dimethylpiperazine-2,3-dithione)platinum(II) tetrafluoroborate 以 乙腈 为溶剂， 以95%的产率得到[Pt(N,N'-dimethyl-piperazine-2,3-dithione)2][Pt(CN)4]
  参考文献：
  名称：

  Salts of cationic platinum dithiolenes with anionic platinum complexes: structural characterization of [Pt(Me2pipdt)2][Pt(SCN)4] (Me2pipdt = N,N′-dimethyl-piperazine-2,3-dithione)

  摘要：

  [Pt(Me(2)pipdt)(2)](BF4)(2) salts [Me(2)pipdt = N,N'-dimethyl-piperazine-2,3-dithione] bearing cationic dithiolene complexes react with (Bu4N)(2)[Pt(X)(4)] (X = SCN, CN) to form [Pt(Me(2)pipdt)(2)][Pt(SCN)(4)] (1) and [Pt(Me(2)pipdt)(2)][Pt(CN)(4)] (2) salts by metathesis. Black crystals of 1 have been structurally characterized showing that the two metals lie on inversion centers and exhibit a square planar coordination. The Pt-S bond distances in the anion complex (2.324(2) Angstrom) are longer than in the cation complex (2.280(2) Angstrom) whereas the C-S bond distances are shorter in SCN- (average 1.669 Angstrom) than in Me(2)pipdt (average 1.694 Angstrom). The chelating Me(2)Pipdt ligand is found disordered in the lambda/delta conformations with site occupancies of 50/50. respectively. The cation and anion complexes run parallel to a. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2003.11.013