Layered Hofmann-type iron(ii) coordination polymers functionalised with 5-aminopyrimidine ligands show gate-opening driven guest-exchange accompanied by drastic structural and spin-crossover modulations.
功能化了5-
氨基嘧啶配体的分层霍夫曼型
铁(II)配位聚合物表现出由门控开启驱动的客体交换,伴随着剧烈的结构和自旋交替调制。