1,8-dimesyloctane | 17039-52-0

• 分子结构分类: 有机化合物 - 有机硫化合物 - 磺酰类
• 英文名称: 1,8-dimesyloctane
• 英文别名: 1,8-bis(methylsulfonyl)octane
• CAS: 17039-52-0
• 化学式: C₁₀H₂₂O₄S₂
• 分子量: 270.414
• InChiKey: ZERWTCPMLNSIHQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  16
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  85
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  (3R,6S)-6-phenylmethoxy-2,3,3a,5,6,6a-hexahydrofuro[3,2-b]furan-3-ol 、 1,8-dimesyloctane 在 四丁基溴化铵 、 potassium hydroxide 作用下， 生成
  参考文献：
  名称：

  Preparation of Polymers under Phase-Transfer Catalytic Conditions

  摘要：

  The application of phase-transfer catalytic (PTC) conditions leading to substantial improvements in numerous polymerization reactions is described. Generally, better yields as well as faster and cleaner reactions are achieved compared to reactions under conventional conditions. Owing to their ionic mechanisms, poly-condensation reactions are the most often applied among polymerization methods under PTC conditions; thus, a number of examples on gram scale are presented in this review.

  DOI：

  10.1021/op100040x