4-(7-Bromo-9,9-dimethylfluoren-2-yl)dibenzofuran | 1186644-60-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并呋喃
• 英文名称: 4-(7-Bromo-9,9-dimethylfluoren-2-yl)dibenzofuran
• CAS: 1186644-60-9
• 化学式: C₂₇H₁₉BrO
• 分子量: 439.351
• InChiKey: QPLDARAAXSBULM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.5
• 重原子数：
  29
• 可旋转键数：
  1
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  13.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  5,10-二氢茚并[3,2-b]吲哚 、 4-(7-Bromo-9,9-dimethylfluoren-2-yl)dibenzofuran 在 potassium phosphate 、 copper(l) iodide 、 trans-1,2-cyclohexanediamine 作用下， 以 1,4-二氧六环 为溶剂， 反应 48.0h， 以6 g的产率得到5-(7-dibenzofuran-4-yl-9,9-dimethylfluoren-2-yl)-10H-indeno[1,2-b]indole
  参考文献：
  名称：

  EP2738166

  摘要：

  公开号：

文献信息

• [EN] MATERIALS FOR ORGANIC ELECTROLUMINESCENT DEVICES<br/>[FR] MATIÈRES POUR DISPOSITIFS ÉLECTROLUMINESCENTS ORGANIQUES
  申请人：MERCK PATENT GMBH

  公开号：WO2017102064A1

  公开（公告）日：2017-06-22

  The present invention relates to compounds of the formula (1) which are suitable for use in electronic devices, in particular organic electroluminescent devices, and to electronic devices which comprise these compounds.

  本发明涉及式（1）的化合物，该化合物适用于电子器件，特别是有机电致发光器件，并且涉及包含这些化合物的电子器件。
• AROMATIC AMINE DERIVATIVE, AND ORGANIC ELECTROLUMINESCENT ELEMENT
  申请人：Yabunouchi Nobuhiro

  公开号：US20110278551A1

  公开（公告）日：2011-11-17

  Provided are an organic electroluminescence device that not only provides high efficiency but also has a long lifetime, and an aromatic amine derivative that realizes the device. The organic electroluminescence device includes an aromatic amine derivative, including at least one substituent A having dibenzofuran and at least one substituent B selected from groups each having dibenzofuran or carbazole, in a molecule thereof, in which the substituent A and the substituent B include groups different from each other, and the substituent A and the substituent B are bonded to the same nitrogen atom, or different nitrogen atoms, in the molecule. The molecules of the aromatic amine derivative hardly crystallize, which improves a yield in the production of the organic electroluminescence device. In the organic electroluminescence device, including an organic thin film layer formed of one or more layers including at least a light emitting layer, the organic thin film layer being interposed between a cathode and an anode, the aromatic amine derivative is contained in at least one layer, particularly a hole transport layer, in the organic thin film layer.

  提供了一种既具有高效率又具有长寿命的有机电致发光器件，以及实现该器件的芳香胺衍生物。该有机电致发光器件包括一种芳香胺衍生物，其中该芳香胺衍生物的分子中包含至少一个具有二苯并呋喃的取代基A和至少一个从具有二苯并呋喃或咔唑的各个基团中选择的取代基B，其中取代基A和取代基B包含不同的基团，并且取代基A和取代基B连接到同一氮原子或不同的氮原子上。该芳香胺衍生物的分子几乎不结晶，从而提高了有机电致发光器件的产量。在包括至少一个发光层的一个或多个层的有机薄膜层中，该有机薄膜层被插入在阴极和阳极之间的有机电致发光器件中，该芳香胺衍生物包含在至少一层中，特别是在空穴传输层中。
• AROMATIC AMINE DERIVATIVES AND ORGANIC ELECTROLUMINESCENT ELEMENTS USING SAME
  申请人：KATO Tomoki

  公开号：US20120146014A1

  公开（公告）日：2012-06-14

  Provided are an organic EL device material that reduce the driving voltage of an organic EL device and increase the lifetime of the device as compared with a conventional organic EL device material. Also provided are organic electroluminescence devices containing the organic EL device material.

  提供了一种有机EL器件材料，与传统有机EL器件材料相比，该材料降低了有机EL器件的驱动电压并增加了器件的使用寿命。同时，还提供了含有该有机EL器件材料的有机电致发光装置。
• NITROGENATED AROMATIC HETEROCYCLIC DERIVATIVE, AND ORGANIC ELECTROLUMINESCENT ELEMENT USING SAME
  申请人：Idemitsu Kosan Co., Ltd

  公开号：EP2738166A1

  公开（公告）日：2014-06-04

  A nitrogen-containing aromatic heterocyclic derivative in which a nitrogen atom of an indenocarbazole skeleton optionally having a hetero atom or an indenoindole skeleton optionally having a hetero atom is bonded to a dibenzofuran or a dibenzothiophene directly or indirectly. The derivative realizes an organic EL device with a high emission efficiency and a long lifetime.

  一种含氮芳香杂环衍生物，其中茚并咔唑骨架（可选择具有一个杂原子）或茚并吲哚骨架（可选择具有一个杂原子）的氮原子直接或间接地与二苯并呋喃或二苯并噻吩键合。该衍生物实现了一种具有高发射效率和长寿命的有机电致发光器件。
• Nitrogenated aromatic heterocyclic derivative, and organic electroluminescent element using same
  申请人：Kato Tomoki

  公开号：US10043977B2

  公开（公告）日：2018-08-07

  A nitrogen-containing aromatic heterocyclic derivative in which a nitrogen atom of an indenocarbazole skeleton optionally having a hetero atom or an indenoindole skeleton optionally having a hetero atom is bonded to a dibenzofuran or a dibenzothiophene directly or indirectly. The derivative realizes an organic EL device with a high emission efficiency and a long lifetime.

  一种含氮芳香杂环衍生物，其中茚并咔唑骨架（可选择具有一个杂原子）或茚并吲哚骨架（可选择具有一个杂原子）的氮原子直接或间接地与二苯并呋喃或二苯并噻吩键合。该衍生物实现了一种具有高发射效率和长寿命的有机电致发光器件。