3,3'-Sulfanediylbis(thietane) | 597580-26-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 硫杂环丁烷
• 英文名称: 3,3'-Sulfanediylbis(thietane)
• 英文别名: 3-(thietan-3-ylsulfanyl)thietane
• CAS: 597580-26-2
• 化学式: C₆H₁₀S₃
• 分子量: 178.3
• InChiKey: OVVUTJCWMFOOQM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  9
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  75.9
• 氢给体数：
  0
• 氢受体数：
  3

文献信息

• CHROMENE COMPOUND, CURABLE COMPOSITION COMPRISING THE COMPOUND, AND OPTICAL ARTICLE INCLUDING A CURED BODY OF THE CURABLE COMPOSITION
  申请人：TOKUYAMA CORPORATION

  公开号：US20200190106A1

  公开（公告）日：2020-06-18

  A chromene compound having at least one indenonaphthopyran moiety which has a group forming a spiro ring together with the 13-position carbon atom and further an oligomer chain group selected from a polyalkylene oxide oligomer chain group having at least three recurring units and a polyester oligomer chain group having at least three recurring units, represented by the following formula and having reduced matrix dependence: wherein R 1 and R 2 are each a group which may have an oligomer chain group, the ring Z bonded to the 13-position carbon atom of the chromene compound is a Spiro ring group, and R 3 and R 4 are each an aryl group or heteroaryl group which may have an oligomer chain group. Preferably, the chromene compound has at least one oligomer chain group in the molecule.

  具有至少一个印苯并萘吡喃基团的色酮化合物，其中该基团与13位碳原子形成螺环，并且进一步具有从至少三个重复单元中选择的聚烷氧基寡聚物链基团和聚酯寡聚物链基团中的一个寡聚物链基团，由下式表示并具有降低的矩阵依赖性： 其中R1和R2是各自可能具有寡聚物链基团的基团，与色酮化合物的13位碳原子键合的环Z是螺环基团，而R3和R4是各自可能具有寡聚物链基团的芳基或杂环基团。最好，该色酮化合物在分子中至少具有一个寡聚物链基团。
• PHOTOCHROMIC COMPOSITION
  申请人：TOKUYAMA CORPORATION

  公开号：US20160222285A1

  公开（公告）日：2016-08-04

  A photochromic composition comprising (A) a polyrotaxane having a composite molecular structure composed of an axial molecule and a plurality of cyclic molecules clathrating the axial molecule and (B) a photochromic compound.

  一种光致变色组合物，包括(A)聚轮烷，其具有由轴向分子和多个环状分子组成的复合分子结构，并且(B)光致变色化合物。
• ADDITIVE FOR POLYMERIZABLE COMPOSITION, POLYMERIZABLE COMPOSITION CONTAINING THE SAME AND USE OF THE POLYMERIZABLE COMPOSITION
  申请人：Ando Tomoyuki

  公开号：US20100286334A1

  公开（公告）日：2010-11-11

  The additive for a polymerizable composition according to the present invention contains a compound represented by the general formula (a). In the general formula (a), R represents a saturated hydrocarbon group having 1 to 3 carbon atoms. M represents Sn, Sb, Bi, or Ge. m represents 0 or 1. R and M are not directly bonded when m is 0. n represents an integer of 1 to 3. X represents a monovalent linking group, and a plurality of X may be the same as or different from each other. When two or more linking groups X are bonded with the metal atom M, the linking groups X may combine together to form a ring.

  本发明的聚合物组成物的添加剂包含由一般式（a）表示的化合物。在一般式（a）中，R表示具有1至3个碳原子的饱和碳氢基团。M表示Sn、Sb、Bi或Ge。m表示0或1。当m为0时，R和M不直接结合。n表示1至3的整数。X表示单价连接基团，多个X可以相同或不同。当两个或更多连接基团X与金属原子M结合时，连接基团X可以组合在一起形成环。
• POLYMERIZABLE COMPOSITION CONTAINING NOVEL CYCLIC SULFUR COMPOUND AND RESIN OBTAINED BY CURING THE POLYMERIZABLE COMPOSITION
  申请人：MITSUI CHEMICALS, INC.

  公开号：EP1482002A1

  公开（公告）日：2004-12-01

  A sulfur-containing compound has a structure represented by formula (1): (wherein R1 represents a hydrogen atom, a reactive terminal group, a straight, branched or cyclic alkyl group having 1 to 10 carbon atoms and a reactive terminal group or its thia derivative thereof, an aryl group, or an aralkyl group; Y represents an oxygen atom, a sulfur atom, a selenium atom, or a tellurium atom; R represents a substituted or unsubstituted bivalent hydrocarbon group having 1 to 10 carbon atoms, which may be thianated; n represents an integer of 0 to 3; X1 is substituted for any one of groups R2 to R7 of a partial structure represented by formula (2) in which the groups R2 to R7 other than the group substituted by X1 are independently a hydrogen atom or a substituted or unsubstituted monovalent hydrocarbon group having 1 to 10 carbon atoms; and R1 is not a group having a (meth)acryl group when Y is an oxygen atom.) The compound has a high refractive index and high Abbe's number, and produces a resin having excellent impact resistance.

  含硫化合物具有由式(1)表示的结构： (其中 R1 代表氢原子、活性末端基团、具有 1 至 10 个碳原子的直链、支链或环状烷基和活性末端基团或其噻吩衍生物、芳基或芳烷基；Y 代表氧原子、硫原子、硒原子或碲原子；R 代表具有 1 至 10 个碳原子的取代或未取代的二价烃基，可被噻烷化；n 代表 0 至 3 的整数；X1 被式(2)所代表的部分结构的基团 R2 至 R7 中的任一个基团取代，其中除被 X1 取代的基团外，R2 至 R7 独立地为氢原子或具有 1 至 10 个碳原子的取代或未取代的一价烃基；当 Y 为氧原子时，R1 不是具有(甲基)丙烯酰基的基团。) 该化合物具有高折射率和高阿贝数，可制成具有优异抗冲击性的树脂。
• POLYMERIZABLE COMPOSITION, RESIN USING THE SAME AND OPTICAL COMPONENT
  申请人：Mitsui Chemicals, Inc.

  公开号：EP2014700A1

  公开（公告）日：2009-01-14

  A polymerizable composition including a compound represented by following General Formula (1): (in Formula (1), M represents a metal atom; X1 and X2 each independently represents a sulfur atom or an oxygen atom; R1 represents a divalent organic group; m represents an integer of 0 or 1 or greater; p represents an integer of 1 to n; n represents a valence of a metal atom M; and Y's each independently represents an inorganic or organic residue, where when n-p is 2 or greater, Y's may be bonded to each other to form a ring containing a metal atom M), and a thiol compound.

  一种可聚合组合物，包括通式（1）所代表的化合物： 式（1）中，M 代表金属原子；X1 和 X2 各自独立地代表硫原子或氧原子；R1 代表二价有机基团；m 代表 0 或 1 或更大的整数；p 代表 1 至 n 的整数；n 代表金属原子 M 的价数；Y's 各自独立地代表无机或有机残基，其中当 n-p 为 2 或更大时，Y's 可相互键合以形成含有金属原子 M 的环），以及 硫醇化合物。