[Th(4-[N-(2'-nitrobenzylidene)amino]antipyrine semicarbazone)2(NCS)4] | 837367-22-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪烷类
• 英文名称: [Th(4-[N-(2'-nitrobenzylidene)amino]antipyrine semicarbazone)2(NCS)4]
• 英文别名: [Th(2'-NO2BAAPS)2(NCS)4]
• CAS: 837367-22-3
• 化学式: C₄₂H₃₈N₁₈O₆S₄Th
• 分子量: 1251.18
• InChiKey: ZCBILSFEJYGKEW-TZQHOQFOSA-N

反应信息

• 作为产物：
  描述：

  thorium(IV) thiocyanate 、 4-[N-(2'-nitrobenzylidene)amino]antipyrine semicarbazone 以 甲醇 为溶剂， 以82%的产率得到[Th(4-[N-(2'-nitrobenzylidene)amino]antipyrine semicarbazone)2(NCS)4]
  参考文献：
  名称：

  Studies on Some Thorium(IV) Complexes with High Coordination Numbers Derived from Semicarbazones of 4‐Aminoantipyrine

  摘要：

  The interaction of thorium(IV) salts with 4 [N-(benzylidene)amino] antipyrine semicarbazone (BAAPS), 4[N-(4-methoxybenzylidene)amino] antipyrine semicarbazone (MBAAPS), 4[N-(4'-dimethoxyaminobenzylidene)amino]antipyrine semicarbazone (DABAAPS), 4[N-(2'-nitrobenzylidene)amino]antipyrine semicarbazone (2'-NO(2)BAAPS), and 4[N-(3'-nitrobenzylidene)amino]antipyrine semicarbazone (3-NO(2)BAAPS) in non-aqueous solvents resulted in the formation of [ThL2X4] (N = Cl, Br, or NCS), [ThL2I2]I-2, [ThL2](ClO4)(2) or [ThL(NO3)(4)] (L = BAAPS, MBAAPS, DABAAPS, 2-NO(2)BAAPS, or 3-NO(2)BAAPS). All of these compounds were characterized by elemental analyses, electrical conductivity, IR, and thermal methods. X-ray powder diffraction studies of a representative complex were also undertaken. Th(IV) displays the coordination numbers 6, 8, 10, and 11 in these compounds depending on the nature of the coordinated anion and the stoichiometry.

  DOI：

  10.1081/sim-200026274