Fe(CO)(PPh3)(η5-C5H4Si(n-Bu)2CH2) | 669048-59-3

• 英文名称: Fe(CO)(PPh3)(η5-C5H4Si(n-Bu)2CH2)
• CAS: 669048-59-3
• 化学式: C₃₃H₃₉FeOPSi
• 分子量: 566.578
• InChiKey: WFFLKMGOQOJLAC-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  Fe(CO)2(η5-C5H4Si(n-Bu)2CH2) 、 三苯基膦 以 正己烷 为溶剂， 以41%的产率得到Fe(CO)(PPh3)(η5-C5H4Si(n-Bu)2CH2)
  参考文献：
  名称：

  Isolation and Ring-Opening of New 1-Sila-3-metallacyclobutanes (η⁵-C₅H₄Fe)(CO)₂CH₂SiR₂ Leading to A New Class of Organometallic Polymer

  摘要：

  Treatment of FpCH2SiR2Cl [Fp = (eta5-C5H5)Fe(CO)2] with lithium diisopropylamide leads to the formation of new metallacycle complexes. When R2 = Me2 and MenBu, these ring-open to form a new class of organometallic polymer. When R2 = nBu2, the metallacycle resists ring-opening and may be structurally characterized as the Ph3P-substituted species.

  DOI：

  10.1021/ja030559+