tris(bis(imino(methoxy)methyl)aminato)cobalt(III) | 57088-36-5

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: tris(bis(imino(methoxy)methyl)aminato)cobalt(III)
• CAS: 57088-36-5
• 化学式: C₁₂H₂₄CoN₉O₆
• 分子量: 449.372
• InChiKey: UXWCOERBGWCFRT-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  cobalt(II) sulfide 、 copper(II) 2,4-methoxy-1,3,5-triazapentadienato 在 air 作用下， 以 二甲基亚砜 为溶剂， 生成 tris(bis(imino(methoxy)methyl)aminato)cobalt(III)
  参考文献：
  名称：

  Tris{bis[imino(methoxy)methyl]aminato}cobalt(III): an electronic analogue of tris(β-diketonates)

  摘要：

  The cobalt(III) complex [Co(HNCOMeNCOMeNH)(3)]. i.e. [CoL(3)], has been prepared from the copper precursor. [CuL(2)] in a Me(2)SO-CoS suspension. Its crystal and molecular structure has been determined by X-ray diffraction (R = 0.0577). The crystal consists of isolated molecules exhibiting a {CoN6) chromophore. In solution the complex is ESR silent. evidencing the absence of Co-II or Cu-II. The ligand L generates a rather strong ligand field (Delta/hc = 21 200 cm(-1)) as follows from an analysis of the electronic spectra.

  DOI：

  10.1039/dt9950001921