| 204861-06-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机碳酸及其衍生物
• CAS: 204861-06-3
• 化学式: C₃H₃NO₃*Cu
• 分子量: 164.608
• InChiKey: BTGQTAFAXKRVRU-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  copper;2-(methylamino)-2-oxoacetate 以 neat (no solvent) 为溶剂， 生成
  参考文献：
  名称：

  Thermal analysis of oxamates, thiooxamates and their complexes

  摘要：

  The article describes the thermal behaviour of Cu(II) complexes formed with ligands R1R2NCXCOOK (R1R2=H or CH3, X=O or S). The oxamates form 2/1 complexes Cu(R1R2NCOCOO)(2) . xH(2)O and deprotonated ionic complexes K2Cu[R2NCOCOO](2) . yH(2)O. These compounds form polymers by thermal decomposition and deprotonation of the primary or secondary amide function. The ligands break at the C-C bond by forming mainly CO2 and oxamides (R1R2NCOCONR1R2), by recombination of the amide functional groups. The thiooxamates also form 2/1 complexes and decompose without forming any other stable compound. (C) 1998 Elsevier Science B.V.

  DOI：

  10.1016/s0040-6031(97)00450-4